6922-39-0Relevant articles and documents
Sokolov et al.
, (1974)
Effects of water and alcohols on the polymerization of furan during its acid-catalyzed conversion into benzofuran
Hu, Xun,Jiang, Shengjuan,Kadarwati, Sri,Dong, Dehua,Li, Chun-Zhu
, p. 40489 - 40501 (2016/05/24)
Furan, an important product from catalytic pyrolysis of biomass, has the potential to be further converted into value-added chemicals or biofuels. This study investigated the conversion of furan into benzofuran over a Br?nsted acid catalyst (Amberlyst 70) at 140-190°C in various solvents. With water as the solvent, furan could barely make its way to benzofuran as its polymerization dominated. With methanol as the solvent, the polymerization of furan was suppressed and benzofuran formation was enhanced substantially. This is because in methanol, the reactive intermediates (i.e., aldehydes) were stabilized and their involvement in polymerization reactions was suppressed. Other alcohols showed similar effects on suppressing polymerization. In dimethyl sulfoxide (DMSO), the polymerization of furan was also effectively suppressed. However, furan was not converted to benzofuran but to levulinic acid via a distinct reaction route.
Anodic α-Methoxylation of Aliphatic Saturated Ethers
Shono, Tatsuya,Matsumura, Yoshihiro,Onomura, Osamu,Yamada, Yasufu
, p. 1099 - 1100 (2007/10/02)
The anodic oxidation of aliphatic saturated ethers carried out in a mixed solvent of methanol and acetic acid gave α-methoxylated ethers in much better yields than those obtained by using only methanol as a solvent.