69561-88-2

Usage

InChI:InChI=1/2C6H5.C3H9Si.Sb/c2*1-2-4-6-5-3-1;1-4(2)3;/h2*1-5H;1-3H3;/rC12H10Sb.C3H9Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-4(2)3/h1-10H;1-3H3

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 50518-68-8 diphenylantimony(III) bromide 
• 2629-47-2 diphenylantimony(III) chloride 
• 7439-95-4 magnesium 
• 603-36-1 triphenylantimony 

Downstream Products

• 16029-98-4 trimethylsilyl iodide 
• 30982-88-8 methyldiphenylstibane 
• 75-77-4 chloro-trimethyl-silane 
• 1825-61-2 Trimethylmethoxysilane 
• 5865-81-6 diphenylstibane 
• 17938-52-2 Diphenylstibino-trimethylsiloxan 
• 74353-17-6 2,3-bis(diphenylstibino)maleic anhydride 
• 74353-18-7 2,3-bis(diphenylstibino)maleic thioanhydride 
• 126703-89-7 diphenyl(trimethylsilylthio)stibane 
• 603-36-1 triphenylantimony 

Relevant academic research and scientific papers

NEUE DARSTELLUNG, SCHWEFELINSERTION UND HYDROLYSE DER PHENYL(TRIMETHYLSILYL)STIBANE

Reaction of Mg and Me3SiCl with Ph2SbCl or PhSbCl2 gives Ph2SbSiMe3 (1) or PhSb(SiMe3)2 (2).Sulfur inserts into 1 to give Ph2SbSSiMe3 (3).Products of action of S8 on 2 are 3, PhSb(SSiMe3)2 (4), (Me3Si)2S, and Sb2S3.Hydrolysis or methanolysis of 1, or 2 give Ph2SbH (5), or PhSbH2 (6), respectively.Key words: Diphenyl(trimethylsilyl)stibane; phenylbis(trimethylsilyl)stibane; diphenyl(trimethylsilyl-thio)stibane; diphenylstibane; phenylstibane.

Reduction of Butyl- and Phenylantimony(III) Bromides and of t-Butylantimony(III) Chlorides with Magnesium in the Presence of Trimethylchlorosilane: Competition of Sb-Sb and Sb-Si Coupling

Butylantimony(III) bromides react with Mg in tetrahydrofuran (THF) even in presence of Me3SiCl exclusively with Sb-Sb-coupling: Starting from Bu2SbBr, Bu2SbSbBu2 is formed and BuSbBr2 is reduced to (BuSb)x.Sb-Si-coupling dominates in the reactions of Ph2SbBr or t-Bu2SbCl with Mg/Me3SiCl/THF yielding Ph2SbSiMe3 or t-Bu2SbSiMe3.Both Sb-Sb- and Sb-Si-coupling reactions are observed, when PhSbBr2 reacts with Mg and Me3SiCl yielding PhSb(SiMe3)2 and (PhSb)x.The same reactants can also form the distibanes Ph2(SiMe3)2Sb2 and PhSb(SiMe3)3Sb2.The reaction of t-BuSbCl2 with Mg/Me3SiCl yields the stibines t-BuSb(SiMe3)2 and Sb(SiMe3)3 together with (t-BuSb)4.In the reactions of t-BuSbCl2 or PhSbBr2 the ratio of Sb-Sb- and Sb-Si-coupling can be strongly influenced by using different reaction conditions. - Keywords: Diphenyl(trimethylsilyl)stibine, Phenylbis(trimethylsilyl)stibine, Di-tert-butyl(trimethylsilyl)stibine, tert-Butyl-bis(trimethylsilyl)stibine

Diphenylarsinoderivatives of Maleic Acid Anhydride and Related Compounds. Crystal and Molecular Structure of 2,3-Bis(diphenylstibino)maleic Acid Anhydride

The unusual properties of bis(diphenylphosphino)maleic anhydride and similar ditertiary phosphines has prompted the synthesis of analogous arsines and stibines.Bis(diphenylarsino)maleic anhydride, -maleic thioanhydride and -N-methyl maleic imide, bis(diphenylstibino)maleic anhydride (5) and -maleic thioanhydride are obtained as crystalline yellow or red compounds by the reaction of the corresponding 2,3-dichloromaleic acid derivatives with diphenyl(trimethylsilyl)arsine and -stibine resp.The uv/vis spectra and characteristic i.r. bands of selected compounds are given and compared with those of the corresponding phosphines.The strong shift of νC=C to lower wavenumbers observed in all compounds has caused the determination of crystal and molecular structure of 5 by x-ray diffraction.Bond distances and angles are given.The complex formation of the new diarsine ligands has been examined by the preparation of Ni-, Cr- and Mo-carbonyl derivatives.As the first organylsulfane substituted maleic acid derivatives bis(phenylthio)maleic thioanhydride, -N-methyl-maleic imide and -maleic acid dimethylester are synthesized and described. - Keywords: Bis(diphenylarsino)maleic acid, derivatives; Bis(diphenylstibino)maleic anhydride, synthesis, crystal structure; Bis(phenylthio)maleic acid, derivatives; Maleic acid derivatives, synthesis, molecular structure