5865-81-6Relevant articles and documents
Rossi, R. A.,Bunnett, J. F.
, p. 112 - 117 (1974)
Electrochemical studies on organometallic compounds XXXVI. New aspects of the electroreduction of (Ph2Sb)2O, (Ph2Sb)2, Ph2Sb(nBu), and Ph3Sb
Mourad, Y.,Mugnier, Y.,Breunig, H.J.,Ates, M.
, p. 85 - 90 (2007/10/02)
Electroreduction of (Ph2Sb)2O (1) in THF gives Ph2Sb-, which can also be obtained by uptake of two electrons on (Ph2Sb)2 (2).Ph2Sb- reacts with the supporting salt (nBu4NPF6) to yield tributylamine and Ph2Sb(nBu) (3).The electroreduction of 3 and Ph3Sb (4) gives also the anion Ph2Sb-.There is a considerable influence of the electrode surface on the redox properties of 1-4.Mechanistic aspects are discussed.