Stibine, diphenyl(trimethylsilyl)-

Base Information

Chemical Name:Stibine, diphenyl(trimethylsilyl)-
CAS No.:69561-88-2
Molecular Formula:C15H19 Sb Si
Molecular Weight:349.151
Hs Code.:
Mol file:69561-88-2.mol

Synonyms:Stibine, diphenyl(trimethylsilyl)-;69561-88-2;Diphenyl(trimethylsilyl)stibin

Suppliers and Price of Stibine, diphenyl(trimethylsilyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Stibine, diphenyl(trimethylsilyl)-

Chemical Property:

PSA：0.00000
LogP:4.68170
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:348.02941
Heavy Atom Count:17
Complexity:151

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)C.C1=CC=C(C=C1)[Sb]C2=CC=CC=C2

Technology Process of Stibine, diphenyl(trimethylsilyl)-

There total 3 articles about Stibine, diphenyl(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 75-77-4
chloro-trimethyl-silane

: 2629-47-2
diphenylantimony(III) chloride

: 7439-95-4
magnesium

: 69561-88-2
diphenyl(trimethylsilyl)stibine

Guidance literature:: In tetrahydrofuran; byproducts: MgCl2; A soln. of Ph2SbCl in THF is added to Mg and Me3SiCl in THF, the mixture is stirred under Ar for 2 h.; evapn. of solvent under vac., residue is washed (ether), removal of solvent, an oil is obtained;

Reference yield: 51.5%

: 75-77-4
chloro-trimethyl-silane

: 603-36-1
triphenylantimony

: 69561-88-2
diphenyl(trimethylsilyl)stibine

Guidance literature:: With lithium; In tetrahydrofuran; a 20-fold excess of Li reacts with Sb(C6H5)3 in THF at room temp. for 20 h under Ar, decanting,treating with t-C4H9Cl, at -20°C, evapn. in vac.; washing with pentane, evapn.;

Reference yield: 24.2%

: 75-77-4
chloro-trimethyl-silane

: 50518-68-8
diphenylantimony(III) bromide

: (C₆H₅)(n)

: 69561-88-2
diphenyl(trimethylsilyl)stibine

: 2654-44-6
tetraphenyldistibane

: 603-36-1
triphenylantimony

Guidance literature:: With magnesium; In tetrahydrofuran; byproducts: MgBrCl; (Ar), Sb-compd. in THF added to Mg-chips, Me3SiCl added dropwise, stirred for 1 h; THF removed at 0.1 mmHg, washed several times with pentane, removed, distilled at 155°C/0.01 mmHg;