69805-79-4

Basic information

• Product Name: N-benzyl-N’,N’-morpholinylurea
• Synonyms: N-benzyl-N’,N’-morpholinylurea
• CAS NO: 69805-79-4
• Molecular Weight: 220.271
• Mol File: 69805-79-4.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: N-benzyl-N’,N’-morpholinylurea(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-N’,N’-morpholinylurea(69805-79-4)
• EPA Substance Registry System: N-benzyl-N’,N’-morpholinylurea(69805-79-4)

Safety Data

• Hazardous Substances Data: 69805-79-4(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 4257-83-4 benzyl 2,2,2-trichloroacetamide 
• 124-38-9 carbon dioxide 
• 100-39-0 benzyl bromide 
• 67-56-1 methanol 
• 100-46-9 benzylamine 
• 102276-50-6 β,β,β-Trichloroethyl Benzylaminoformate 
• 104669-74-1 benzyl carbamic acid allyl ester 
• 23328-69-0 4-chloromorpholine 
• 88333-03-3 Benzyl isocyanide 
• 39896-97-4 benzyl-carbamic acid benzyl ester 
• 5330-97-2 N-hydroxy-2-phenylacetamide 
• 25180-84-1 N-benzylmorpholine-4-carbothioamide 
• 93605-74-4 4-[(1H-imidazol-1-yl)carbonyl]morpholine 

Relevant articles and documents

N-functionalized benzotriazole-1-carboximidoyl chlorides: Synthetic equivalents for isocyanide dichlorides

Readily prepared N-functionalized benzotriazole-1-carboximidoyl chlorides are proposed as stable and novel isocyanide dichloride synthetic equivalents. Subsequent condensations of these new intermediates afford polysubstituted guanidines, S-aryl isothiour

METHOD OF CONVERTING CARBON DIOXIDE INTO CARBONYL COMPOUNDS

The present invention provides a method for fixing carbon dioxide gas as a carbonyl compound represented by formula (3) as depicted by Figure 1 and comprising, purging of carbon dioxide in a solution of a nucleophile represented by the formula (1) in presence of a solvent at a temperature ranging from -40 Degree Celsius to 35 Degree Celsius, followed by adding a reagent at temperature ranging from -40 degree to 35 degree and thereafter adding another nucleophile represented by the formula (2) to obtain carbonyl compound represented by formula (3). The present invention can be advantageously used to obtain commercially important carbonyl compounds and clean unwanted carbon dioxide gas from the atmosphere and industrial effluents.

Facile direct synthesis of unsymmetrical ureas from N-Alloc-, N-Cbz-, and N-Boc-protected amines using DABAL-Me3

A practical synthetic method for the direct synthesis of unsymmetrically substituted ureas from N-Alloc-, N-Cbz-, and N-Boc-protected amines is described. In this study, efficient direct conversion of the Alloc-, Cbz-, and Boc-carbamate compounds to ureas was achieved in the presence of DABAL-Me3, an air stable and easily handled reagent. Using this reaction method, both protected aromatic and aliphatic amines were successfully transformed into various trisubstituted and tetrasubstituted ureas with high yields without side product. Our findings offer promising guidelines for direct preparation of useful ureas from N-Alloc-, N-Cbz-, and N-Boc-carbamates.