700-75-4

Basic information

• Product Name: 2-methyltricyclo[3.3.1.1~3,7~]decane
• Synonyms: 2-Methyladamantane; tricyclo[3.3.1.1~3,7~]decane, 2-methyl-; Tricyclo[3.3.1.1]decane, 2-methyl-
• CAS NO: 700-75-4
• Molecular Formula: C₉H₁₃NO
• Molecular Weight: 151.2056
• Mol File: 700-75-4.mol
• Article Data: 23

Chemical Properties

• Refractive Index: 1.536
• CAS DataBase Reference: 2-methyltricyclo[3.3.1.1~3,7~]decane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyltricyclo[3.3.1.1~3,7~]decane(700-75-4)
• EPA Substance Registry System: 2-methyltricyclo[3.3.1.1~3,7~]decane(700-75-4)

Safety Data

• Hazardous Substances Data: 700-75-4(Hazardous Substances Data)

Upstream product

• 70329-19-0 tri-N-methyl-o-anisidinium; iodide 
• 50-00-0 formaldehyd 
• 90-04-0 2-methoxy-phenylamine 
• 91-16-7 1,2-dimethoxybenzene 
• 3585-33-9 lithium dimethylamide 
• 141814-27-9 2-(2-Methoxyethoxy)ethyl methyl carbonate 
• 124-38-9 carbon dioxide 
• 10541-78-3 2-methoxy-N-methylaniline 
• 74-88-4 methyl iodide 
• 529-28-2 4-iodoanisol 
• 124-40-3 dimethyl amine 
• 610-16-2 N,N-dimethylanthranilic acid 
• 681-84-5 tetramethylorthosilicate 
• 95-55-6 2-amino-phenol 

Downstream Products

• 70329-19-0 tri-N-methyl-o-anisidinium; iodide 
• 144654-10-4 2-methyl(2-methoxyphenyl)-amino-4,6-difluoro-s-triazine 
• 263917-74-4 (2-methoxyphenyl)methylphenylamine 
• 107480-53-5 N-(2-methoxyphenyl)-N-methylbenzamide 
• 1247605-02-2 C₁₀H₁₂N₂O 
• 70823-88-0 trans-dichloro di(ortho N-methylaminotoluene) palladium(II) 
• 72198-11-9 3-dimethylamino-4-methoxyaniline 
• 136063-65-5 N,N-dimethyl-4-propylthio-o-anisidine 
• 136063-66-6 [2-Methoxy-4-(propane-1-sulfinyl)-phenyl]-dimethyl-amine 
• 106652-41-9 2-methoxy-N-methyl-4,6,N-trinitro-aniline 
• 98488-57-4 N-methyl-2'-methoxy-4',6'-dinitroaniline 
• 7501-46-4 N,N-dimethyl-2-methoxy-5-nitroaniline 

Relevant articles and documents

Dirhodium-Catalyzed Chemo-and Site-Selective C-H Amidation of N, N-Dialkylanilines

A method for dirhodium-catalyzed C(sp 3)-H amidation of N, N-dimethylanilines was developed. Chemoselective C(sp 3)-H amidation of N-methyl group proceeded exclusively in the presence of C(sp 2)-H bonds of the electron-rich aromatic ring. Site-selective C(sp 3)-H amidation proceeded exclusively at the N-methyl group of N-methyl-N-Alkylaniline derivatives with secondary, tertiary, and benzylic C(sp 3)-H bonds α to a nitrogen atom.

Mn-Catalyzed Selective Double and Mono-N-Formylation and N-Methylation of Amines by using CO2

Functionalization of amines by using CO2 is of fundamental importance considering the abundance of amines and CO2. In this context, the catalytic formylation and methylation of amines represent convenient and successful protocols for selective CO2 utilization as a C1 building block. This study represents the first example of selective catalytic double N-formylation of aryl amines by using a dinuclear Mn complex in the presence of phenylsilane. This robust system also allows for selective formylation and methylation of amines under a range of conditions.

Diverse catalytic reactivity of a dearomatized PN3P?-nickel hydride pincer complex towards CO2 reduction

A dearomatized PN3P?-nickel hydride complex has been prepared using an oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selective methylation and formylation of amines with CO2 were demonstrated by such a PN3P?-nickel hydride complex, highlighting its versatile functions in CO2 reduction.