71087-82-6Relevant academic research and scientific papers
Visible Light Irradiation of Acyl Oxime Esters and Styrenes Efficiently Constructs β-Carbonyl Imides by a Scission and Four-Component Reassembly Process
Cheng, Yuan-Yuan,Lei, Tao,Su, Longlong,Fan, Xiuwei,Chen, Bin,Tung, Chen-Ho,Wu, Li-Zhu
supporting information, p. 8789 - 8794 (2019/11/03)
Acyl radical triggered difunctionalizations of aryl olefins have been realized using oxime ester as the acyl precursor for the first time. Irradiation of fac-Ir(ppy)3 and oxime ester by visible light caused scission into three components, which recombined with olefins to yield significant β-carbonyl imides showing good functional group tolerance and high atom economy. Control experiments as well as spectroscopic and electrochemical studies revealed the efficient intermolecular reorganization of oxime ester into styrene with the aid of solvent exchange.
Photocatalytic C-C Bond Activation of Oxime Ester for Acyl Radical Generation and Application
Fan, Xiuwei,Lei, Tao,Chen, Bin,Tung, Chen-Ho,Wu, Li-Zhu
, p. 4153 - 4158 (2019/06/08)
A unified strategy to generate acyl radical from oxime ester via selective C-C bond activation is reported. Under visible-light irradiation, single-electron transfer from fac-Ir(ppy)3 to related oxime takes place followed by a fast β-fragment of C-C bond to yield aryl and aliphatic acyl radicals, subsequently captured by diverse Michael acceptors. More interestingly, the single-electron transfer enables coupling with energy transfer of the excited fac-Ir(ppy)3 via enone intermediate formed in situ for cyclobutane formation.
