71189-80-5Relevant academic research and scientific papers
Alkoxo bridged heterobimetallic CoIIISnIV compounds with face shared coordination octahedra: Synthesis, crystal structure and cyanosilylation catalysis
Hazra, Susanta,Karmakar, Anirban,Pombeiro, Armando J. L.,da Silva, M. Fátima C. Guedes
, (2021)
The self-assembly reaction of the Schiff base N,N’-ethylenebis(2-hydroxyacetophenoneimine) (H2L), CoCl2··6H2O and [SnPh2Cl2] led to the alkoxo-bridged heteroorganometallic CoIIISnIV/s
Tunable morphology and the changeable catalytic property of layered scandium coordination polymer
Zhu, Ziqian,Tong, Chengxia,Wang, Pengcheng,Wang, Wei,Sun, Jing,Xue, Jingjing,Wang, Li,Fan, Yong,Xu, Jianing
, (2020)
Sc-CP 1, 1A, 1B and 1C with controllable morphologies were successfully synthesized by the conventional hydrothermal method and microwave (MW) assisted hydrothermal method. 1 was macroscopic, 1A was nano sized, while 1B and 1C were micron sized. Sc-CP 1 s
Porous Cu(II)-organic framework for solvent-free cyanosilylation and anti-gastric cancer activity by inducing cell apoptosis
Fan, Shi-Jie,Sun, Ren,Li, Di,Liu, Yang
, p. 2855 - 2865 (2020)
A novel metal–organic framework (MOF) containing Cu(II) ions with the chemical formula of {[Cu(L)2(H2O)2](DMF)3}n (1) was successfully prepared by solvothermal reaction method using metal Cu2+/s
One-pot cascade syntheses of microporous and mesoporous pyrazine-linked covalent organic frameworks as Lewis-acid catalysts
Ma, Yunchao,Liu, Xiaozhou,Guan, Xinyu,Li, Hui,Yusran, Yusran,Xue, Ming,Fang, Qianrong,Yan, Yushan,Qiu, Shilun,Valtchev, Valentin
, p. 7352 - 7357 (2019)
Covalent organic frameworks (COFs) are crystalline porous solids with broad potential applications. So far, the successful construction of COFs has been limited to a few condensation reactions, and nearly all COFs were obtained by single-step synthesis based on predesigned linkers. Here, we report a general strategy in view of a one-pot cascade reaction to prepare both microporous and mesoporous fully π-conjugated pyrazine-linked COF materials (PZ-COFs). The obtained PZ-COFs show high chemical stability, large specific surface areas and promising H2, CH4 and CO2 uptake capacities. Furthermore, we demonstrate that manganese(ii)-incorporated PZ-COFs can act as excellent Lewis-acid catalysts for the cyanosilylation of aromatic aldehydes. This study not only provides a facile method to synthesize COFs required for multistep reactions but also expands the applications of COFs as promising catalysts.
A new heterometallic MOF in cyanosilylation reaction, treatment and care management value in stroke by reducing oxidative stress damage
Chen, Shu-Rong,Li, Yi,Wu, Bi-Yu,Xu, Hui
, p. 43 - 49 (2020)
By employment the heterometallic strategy, a new highly porous metal-organic framework {(Me2NH2)[Mn3K2(TZIA)3-(H2O)3] '(DMF)4}n (1) was prepared via corresponding K(I)
New Co(II)-organic framework for cyanosilylation reactions and treatment effect against esophageal cancer by inhibiting cancer cell viability, migration, and invasion
Du, Nan,Huang, Yongdong,Liu, Zihao,Wang, Changgao,Wang, Xiaoman,Zan, Hui
, p. 1 - 14 (2020)
A new metal–organic framework with the chemical formula [Co2(ptptc)·(H2O)3](MeOH) (1) was synthesized using Co(NO3)2· 6H2O and terphenyl-3,3″,5,5″-tetracarboxylic acid (H4ptptc)
Pyrene carboxylate ligand based coordination polymers for microwave-assisted solvent-free cyanosilylation of aldehydes
Da Silva, M. Fátima C. Guedes,Karmakar, Anirban,Paul, Anup,Pombeiro, Armando J. L.,Sabatini, Elia Pantanetti
, (2021)
The new coordination polymers (CPs) [Zn(μ-1κO1:1κO2-L)(H2O)2]n·n(H2O) (1) and [Cd(μ4-1κO1O2:2κN:3,4κO3-L)(H2O)]n·n(H2
Role of metal center and coordination environment in M-(Z)-N-((E)-pyridin-2-ylmethylene)isonicotinohydrazonate (M = LaIII, ZnII, CdII or HgII) catalyzed cyanosilylation of aldehydes
Hajiyeva, Sevinc R.,Huseynov, Fatali E.,Kopylovich, Maximilian N.,Mahmoudi, Ghodrat,Nikitina, Eugeniya V.,Prisyazhnyuk, Ekaterina D.,Shamilov, Nazim T.,Zubkov, Fedor I.
, (2021/09/07)
A series of known metal complexes, [LaL2(NO3)(H2O)2]·5H2O (1), [Zn(μ-L)(NO3)(H2O)]n (2), {[Cd2(μ-HL)(μ-L)(NO3)3(H2O)]·Hsub
Cyanosilylation of carbonyl compounds catalyzed by half-sandwich (η6-p-cymene) Ruthenium(II) complexes bearing heterocyclic hydrazone derivatives
Alves, Luis G.,Bharathi, Madheswaran,Indira, Sekar,Martins, Ana M.,Shanmuga Bharathi, Kuppannan,Vinoth, Govindasamy
, (2020/10/02)
A new class of half-sandwich (?6-p-cymene) ruthenium(II) complexes supported by heterocyclic hydrazone derivatives of general formula [Ru(?6-p-cymene)(Cl)(L)] where L represents N’-((1H-pyrrol-2-yl)methylene)furan-2-carbohydrazide (L
Organo-catalyzed Michael addition of 2-fluoro-2-arylacetonitriles
Chen, De-Yin,Song, Shuai,Chen, Ling-Yan,Ren, Xinfeng,Li, Ya
supporting information, (2021/03/01)
An efficient synthesis of a variety of 2-arylacetonitriles containing a fluorinated stereogenic center through organo-catalyzed Michael addition reaction of 2-fluoro-2-arylacetonitriles has been developed. This protocol uses a cheap organocatalyst (DBU) and has a broad substrate scope: α, β-unsaturated ketones, esters, nitriles and sulfones were all successfully reacted. Importantly, water proved to be a good solvent for this reaction.
