71919-91-0

Basic information

• Product Name: 1-Hexanone, 6-iodo-1-phenyl-
• CAS NO: 71919-91-0
• Molecular Formula: C12H15IO
• Molecular Weight: 302.155
• Mol File: 71919-91-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-Hexanone, 6-iodo-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Hexanone, 6-iodo-1-phenyl-(71919-91-0)
• EPA Substance Registry System: 1-Hexanone, 6-iodo-1-phenyl-(71919-91-0)

Safety Data

• Hazardous Substances Data: 71919-91-0(Hazardous Substances Data)

Upstream product

• 1589-60-2 1-phenylcyclohexanol 
• 20614-61-3 cyclohexyl-1-phenyl-1-hydroperoxide 
• 82777-11-5 6-bromo-1-phenyl-1-hexanone 
• 946-01-0 ε-chlorohexanophenone 

Downstream Products

• 942-92-7 caprophenone 
• 4471-05-0 1-phenylhexan-1-ol 
• 22524-25-0 1-phenylhex-5-en-1-one 
• 98-86-2 acetophenone 

Relevant articles and documents

Copper-catalyzed radical ring-opening halogenation with HX

An efficient copper-catalyzed radical ring-opening halogenation with HX (aq) is described. This protocol features redox-neutral conditions, green halogen sources, and a broad substrate scope, providing practical access to distally chlorinated, brominated and iodinated alkyl ketones and alkyl nitriles with moderate to good yields. This journal is

Ring-opening iodination and bromination of unstrained cycloalkanols through ?-scission of alkoxy radicals

Ring-opening iodination or bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)2 under visible light irradiation is developed. In this protocol the concentration of I2is modulated through the generation of triiodide (I3-), thus significantly avoiding undesired side reactions. The reaction is under mild conditions and has a wide substrate scope, thus providing a practically useful method for accessing ω-iodo or ω-bromoketones.

Catalytic asymmetric intramolecular homologation of ketones with α-diazoesters: Synthesis of cyclic α-Aryl/Alkyl β-ketoesters

A catalytic asymmetric intramolecular homologation of simple ketones with α-diazoesters was firstly accomplished with a chiral N,N′-dioxide-Sc(OTf)3 complex. This method provides an efficient access to chiral cyclic α-aryl/alkyl β-ketoesters containing an all-carbon quaternary stereocenter. Under mild conditions, a variety of aryl- and alkyl-substituted ketone groups reacted with α-diazoester groups smoothly through an intramolecular addition/rearrangement process, producing the β-ketoesters in high yield and enantiomeric excess.