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20614-61-3

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20614-61-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 20614-61-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,0,6,1 and 4 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 20614-61:
(7*2)+(6*0)+(5*6)+(4*1)+(3*4)+(2*6)+(1*1)=73
73 % 10 = 3
So 20614-61-3 is a valid CAS Registry Number.
InChI:InChI=1/C12H16O2/c13-14-12(9-5-2-6-10-12)11-7-3-1-4-8-11/h1,3-4,7-8,13H,2,5-6,9-10H2

20614-61-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name (1-hydroperoxycyclohexyl)benzene

1.2 Other means of identification

Product number -
Other names Hydroperoxide,1-phenylcyclohexyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:20614-61-3 SDS

20614-61-3Relevant articles and documents

Hydroperoxidation of tertiary alkylaromatics catalyzed by N-hydroxyphthalimide and aldehydes under mild conditions

Melone, Lucio,Gambarotti, Cristian,Prosperini, Simona,Pastori, Nadia,Recupero, Francesco,Punta, Carlo

, p. 147 - 154 (2011)

A metal-free catalytic system consisting of an aldehyde and N-hydroxyphthalimide (NHPI) for the selective oxidation of tertiary alkylaromatics with molecular oxygen has been developed. Cumene was oxidized efficiently to the corresponding hydroperoxide under mild conditions. The molecule-induced homolysis between peracids generated in situ and NHPI ensured the formation of the phthalimide N-oxyl (PINO) radical even at room temperature. Investigations on aldehyde, solvent and temperature effects allowed us to achieve good conversions with high selectivity in hydroperoxide. The optimized procedure was successfully extended to phenylcyclohexane, a valuable alternative for the production of phenol. The mechanism is discussed in detail.

Benzylic Hydroperoxidation via Visible-Light-Induced Csp3-H Activation

Inoa, Joan,Patel, Mansi,Dominici, Grecia,Eldabagh, Reem,Patel, Anjali,Lee, John,Xing, Yalan

, p. 6181 - 6187 (2020/05/22)

A highly efficient benzylic hydroperoxidation has been realized through a visible-light-induced Csp3-H activation. We believe that this reaction undergoes a direct HAT mechanism catalyzed by eosin Y. This approach features the use of a metal-free catalyst (eosin Y), an energy-economical light source (blue LED), and a sustainable oxidant (molecular oxygen). Primary, secondary, and tertiary hydroperoxides as well as silyl, benzyl, and acyl peroxides were successfully prepared with good yields and excellent functional group compatibility.

Conjugated copper(II) porphyrin polymer and N-hydroxyphthalimide as effective catalysts for selective oxidation of cyclohexylbenzene

Tan, Zhiwei,Zhu, Junhui,Yang, Weijun

, p. 60 - 64 (2017/03/09)

A nanomaterial catalyst of azo-bridged Cu(II) porphyrin polymer (CuII-APP) was synthesized and characterized by scanning electron microscopy, transmission electron microscopy and N2adsorption measurement. CuII-APP had a nanoporous structure, with the particle size of about 30?nm. Owing to the special structure, CuII-APP acted as an efficient heterogeneous catalyst for selective oxidation of cyclohexylbenzene into cyclohexylbenzene-1-hydroperoxide. When N-hydroxyphthalimide was used as co-catalyst, this binary catalyst system showed an obvious synergic effect. After being recovered and reused, CuII-APP and NHPI still had high catalytic activities.

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