71982-21-3Relevant academic research and scientific papers
Carboxamides as N-Alkylating Reagents of Secondary Amines in Indium-Catalyzed Reductive Amination with a Hydrosilane
Ogiwara, Yohei,Shimoda, Wataru,Ide, Keisuke,Nakajima, Takumi,Sakai, Norio
supporting information, p. 2866 - 2870 (2017/06/06)
A method for the catalytic reductive N-alkylation of amines by using secondary amides as the alkyl source was developed. A versatile type of carboxamide functioned as an N-alkylation reagent in the presence of an indium(III) catalyst and a hydrosilane to provide alkylated tertiary amines efficiently. This amide-based catalytic N-alkylation strategy is considered to be a highly useful protocol to access unsymmetrical tertiary amines.
Iron-catalysed tandem isomerisation/hydrosilylation reaction of allylic alcohols with amines
Li, Haoquan,Achard, Mathieu,Bruneau, Christian,Sortais, Jean-Baptiste,Darcel, Christophe
, p. 25892 - 25897 (2014/07/07)
An iron(0)-catalysed cascade synthesis of N-alkylated anilines from allylic or homoallylic alcohols and primary and secondary anilines under hydrosilylation conditions has been developed. Notably, a simple Fe(cod)(CO)3 complex (cod = cycloocta-
Ruthenium-catalyzed reductive amination of allylic alcohols
Sahli, Zeyneb,Sundararaju, Basker,Achard, Mathieu,Bruneau, Christian
supporting information; experimental part, p. 3964 - 3967 (2011/09/21)
Straighforward access to various saturated amines from allylic alcohols and isostructural mixture can now be achieved in the presence of arene ruthenium catalyst featuring phosphinesulfonate ligand and a hydrogen donor.
One-pot synthesis of secondary and tertiary amines by carbonylative hydroaminomethylation of alkenes catalyzed by di(μ-chloro)bis(η4-1,5-cyclooctadiene)dirhodium
Rische,Eilbracht
, p. 1331 - 1337 (2007/10/03)
Secondary and tertiary amines are selectively prepared with high yields by the reaction of alkenes with primary or secondary amines, carbon monoxide and hydrogen in the presence of [Rh(cod)Cl]2 as catalyst via a one-pot hydroformylation - amine
