7217-41-6

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 625-98-9 3-chlorofluorobenzene 
• 1073-06-9 3-fluorobromobenzene 
• 128254-27-3 2-Fluoro-1,4-bis-trimethylsilanyl-benzene 

Downstream Products

• 345-83-5 4-fluorobenzophenone 
• 345-69-7 3-fluorobenzophenone 
• 701-27-9 3-fluorobenzene-1-sulfonyl chloride 
• 1121-86-4 1-Fluoro-3-iodobenzene 
• 1524-40-9 3-fluorobenzenesulfonyl amide 
• 128254-29-5 (2-Fluoro-4-trimethylsilanyl-phenyl)-phenyl-methanone 
• 455-36-7 1-(3-fluorophenyl)ethanone 
• 462-06-6 fluorobenzene 
• 34557-54-5 methane 
• 41866-81-3 trimethylsiloxide anion 
• 130043-78-6 Sodium; 3-fluoro-benzenesulfonate 
• 1234714-98-7 C₂₀H₂₀FNO₃ 
• 62476-44-2 3-Fluor-1,4-dihydrotrimethylsilylbenzol 
• 130043-77-5 1-(3-Fluoro-phenyl)-3-methyl-but-2-en-1-one 

Relevant academic research and scientific papers

Generation of Aryllithium Reagents from N -Arylpyrroles Using Lithium

Treatment of 1-aryl-2,5-diphenylpyrroles with lithium powder in tetrahydrofuran at 0 °C results in the generation of the corresponding aryllithium reagents through reductive C-N bond cleavage.

Preparation method of aromatic silicon organic compound

The invention provides a preparation method of an aromatic silicon organic compound. The aromatic silicon organic compound is a compound as shown in a formula 3 shown in the specification, the aromatic silicon organic compound is prepared by reacting a compound as shown in a formula 1 with a compound as shown in a formula 2, and the reaction formula is as shown in the specification. In the formulas, a is selected from any integer of 0-5, n is selected from any integer of 1-6, R is selected from one of alkyl, alkoxy, fluorine, trifluoromethyl and trifluoromethoxy; m is any integer selected from 1-3, and R2 is selected from C1-C6 alkyl; a catalyst used in the reaction is MIc, MIc is iodized salt, M is metal ion, and c is selected from 1 or 2 according to the valence state of M; and magnesium is added in the reaction process. The method has the advantages of low cost, effective avoidance of heavy metal residues, simplicity and convenience in operation, high yield, mild reaction conditions and easiness in industrialization.

Arylsilanes: Application to gold-catalyzed oxyarylation of alkenes

Arylsilanes are efficient reagents for the gold-catalyzed oxyarylation of alkenes (21 examples, up to 85% isolated yield). Using commercially available Ph3PAuCl and readily prepared, benign arylsilanes, these two- and three-component reactions

Synthetic applications of fluorinated phenyllithiums: Preparation of fluorinated α-methylstyrenes, benzhydrols, benzophenones and aryltrimethylsilanes

Regioselective preparations of a number of fluorinated phenyllithiums have recently been reported, which in some cases also contain one or more bromine substituents. These have now been applied to the synthesis of the corresponding halogenated 2-arylpropenes (α-methyl-styrenes), benzhydrols, trifluoromethylbenzhydrols, benzophenones and aryltrimethylsilanes.

UNE VOIE ORIGINALE ET SELECTIVE DE FONCTIONNALISATION EN POSITION META DU FLUORO- ET DE L'ETHYLBENZENE

An original and regioselective method for the meta functionalisation of fluoro- and ethylbenze is reported.This process involves a 2,5-disilylation of these subtrates using trimethylchlorosilane in the presence of lithium in THF as the solvent.After aromatisation, monodesilylation in position 2- and electrophilic substitution of the trimethylsilyl group in position 5-, meta acetyl-, senecioyl-, benzoyl-, and iodofluorobenzenes and ethylbenzenes as well as the sodium salts of metafluoro or meta ethylbenzenesulfonic acid and 3-aminosulfonylfluorobenzene were obtained in good yields. pair of diastereomeric triamines 15 and 16.A tricyclic diazasystem 19 was formed from the reaction of cyanide with the carbamoylated chloroenamine 18.Monochloroenamine 10a and dichloroenamine 12a showed a significant mutagenic behaviour in the Ames test.