Journal of the American Chemical Society p. 16124 - 16127 (2014)
Update date:2022-07-30
Topics: Oxidation Hydroboration Work-Up Sulfonation
Xu, Kun
Khakyzadeh, Vahid
Bury, Timm
Breit, Bernhard
A new strategy for the transformation of terminal alkynes to branched allylic sulfones was developed. Using a Rh(I)/DPEphos/benzoic acid catalyst system, terminal alkynes react with sulfonyl hydrazides to produce branched allylic sulfones with good to exc
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