72422-64-1

Upstream product

• 94563-22-1 methyl 2-tributylstannyl-1-cyclohexene-1-carboxylate 
• 186581-53-3 diazomethane 
• 68965-62-8 2-bromocyclohex-1-enecarboxylic acid 
• 67-56-1 methanol 
• 38127-47-8 2-bromocyclohex-1-ene-1-carbaldehyde 

Downstream Products

• 2436-96-6 1-nitro-2-(2-nitrophenyl)benzene 
• 857674-69-2 2-(4,5-dimethoxy-3,6-dioxocyclohexa-1,4-dienyl)cyclohex-1-ene-1-carboxylic acid methyl ester 
• 857674-75-0 2-(2,5-dihydroxy-3,4-dimethoxyphenyl)cyclohex-1-ene-1-carboxylic acid methyl ester 
• 52850-98-3 5-methyl-7,8,9,10-tetrahydrophenanthridin-6(5H)-one 
• 552857-10-0 2-bromo-N-phenyl-1-cyclohexene-1-carboxamide 
• 552857-08-6 2-bromo-N-methyl-N-phenyl-1-cyclohexene-1-carboxamide 
• 857674-63-6 2-(2,3,4,5-tetramethoxyphenyl)cyclohex-1-ene-1-carboxylic acid methyl ester 
• 68965-62-8 2-bromocyclohex-1-enecarboxylic acid 

Relevant academic research and scientific papers

Short and general method for the synthesis of 2-halocycloalk-1- enecarboxylic esters from 2-halocycloalk-1-enecarbaldehydes

One step general method for the synthesis of methyl 2- halocycloalk-1-ene carboxylate derivatives is described by oxidative esterification of 2-halocycloalk-1-enecarbaldehyde derivatives with V2O 5H2O2 in methan

A new fluorogenic transformation: Development of an optical probe for coenzyme Q

(Chemical Equation Presented) A new fluorogenic transformation based on a quinone reduction/lactonization sequence has been developed and evaluated as a tool for probing redox phenomena in a biochemical context. The probe presented herein is an irreversible redox probe and is reduced selectively by biologically relevant quinols such as ubiquinol but is inert to reduced nicotinamides (e.g., NADH). The ensuing cyclization is fast and quantitative and provides a measurable optical response.

CYCLOADDITIONS OF ACETYLENIC ORGANOTINS : SYNTHETIC APPLICATIONS OF POLYFUNCTIONAL CYCLIC VINYLTINS

A novel preparation of functional vinyltins is described.It involves the regiospecific cycloaddition of functional alkynyltins with dienes such as 1,3-butadiene, 2,3-dimethyl-1,3-butadiene or 1-substituted 1,3-butadienes.These cyclic vinyltins, bearing an ester, ketone, amide or nitrile group are converted into carbonylated, halogenated or sulfurized compounds.After reduction of the ester or ketone group, transmetallation leads to functional 1,4-cyclohexadienyllithium which react easily with carbon dioxide, aldehydes or ketones to give substituted 1(3H)-4,7-dihydro-isobenzofuranones or 1,4-diols. ofuranones or 1,4-diols.