72572-79-3

Basic information

• Product Name: 1-methoxy-1-methyl-allyl hydroperoxide
• Synonyms: 1-methoxy-1-methyl-allyl hydroperoxide
• CAS NO: 72572-79-3
• Molecular Weight: 118.133
• Mol File: 72572-79-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-methoxy-1-methyl-allyl hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-1-methyl-allyl hydroperoxide(72572-79-3)
• EPA Substance Registry System: 1-methoxy-1-methyl-allyl hydroperoxide(72572-79-3)

Safety Data

• Hazardous Substances Data: 72572-79-3(Hazardous Substances Data)

Upstream product

• 78-79-5 isoprene 

Downstream Products

• 107-31-3 Methyl formate 
• 79-20-9 acetic acid methyl ester 
• 10027-72-2 methoxymethyl hydroperoxide 
• 87742-47-0 methoxymethylhydroxymethylperoxide 
• 67-56-1 methanol 
• 67-68-5 dimethyl sulfoxide 
• 78-94-4 methyl vinyl ketone 
• 109-87-5 Dimethoxymethane 
• 4461-52-3 methoxymethanol 
• 107729-20-4 1-hydroxy-1-methoxypropan-2-one 

Relevant articles and documents

Monoozonolyses of Acyclic Conjugated Dienes

Monoozonolyses of isoprene (1a), 2-methyl-3-phenyl-1,3-butadiene (1b), 2,3-diphenyl-1,3-butadiene (25), and 2,3,4,5-tetramethyl-2,4-hexadiene (34) have been examined in pentane and in methanol.The dienes 1a, b and 25 afforded all possible α,β-unsaturated monoozonides and α,β-unsaturated methoxy hydroperoxides, respectively, whereas diene 34 gave no ozonide and no α,β-unsaturated methoxy hydroperoxide.From the dienens 25 and 34, the corresponding monoepoxides have been formed additionally.The results allow some conclusions concerning the regioselectivity of ozone attack at the unsymmetrically substituted dienes 1a, b as well as concerning the cleavage directions of primary ozonides.