73130-06-0Relevant articles and documents
Synthesis of N-Sulfonyl Pyrazoles Through Cyclization Reactions of Sulfonyl Hydrazines with Enaminones Promoted by p-TSA
Zhang, Qiaohe,Hu, Biao,Zhao, Yuxuan,Zhao, Siyun,Wang, Yanqin,Zhang, Biao,Yan, Shengjiao,Yu, Fuchao
, p. 1154 - 1159 (2020/02/27)
A strategy for the rapid synthesis of 3-substituted N-sulfonyl pyrazoles via p-TSA-promoted cyclization reactions of sulfonyl hydrazines with N,N-dimethyl enaminones has been developed. This method achieves both the formation of pyrazole ring and the cont
Method for synthesis of substituted 1-sulfonyl-1H-pyrazole
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Paragraph 0037; 0038; 0039; 0040; 0041, (2017/10/07)
The invention discloses a method for synthesis of substituted 1-sulfonyl-1H-pyrazole, and aims to provide a method for synthesis of 1-sulfonyl-1H-pyrazole, the method has the advantages of simple and easily available starting materials, high yield and easy operation, the method is characterized in that sulfonyl hydrazone, N, N-dimethylmalononitrile and a Lewis acid catalyst are in turn added into an organic solvent for heating refluxing reaction to obtain the substituted 1-sulfonyl-1H-pyrazole, and the method belongs to the organic synthesis technical field.
Synthesis of sulfonamides from azoles and sodium sulfinates at ambient temperature
Fu, Lili,Bao, Xiaodong,Li, Shanshan,Wang, Lingtian,Liu, Zhiguo,Chen, Wanzhi,Xia, Qinqin,Liang, Guang
, p. 2504 - 2511 (2017/04/03)
NBS or NIS mediated direct S[sbnd]N bond formation between azoles and sodium sulfinates is described. The reaction shows good substrate scope and tolerates a wide range of functionalities in both azoles and sodium sulfinate substrates. Pyrazoles are also suitable for this method, various 4-halopyrazoles derivatives were obtained by using N-halosuccinimide (NXS) as the halogen source.