74332-02-8Relevant academic research and scientific papers
Direct acetoxylation and etherification of anilides using phenyliodine bis(trifluoroacetate)
Liu, Huan,Wang, Xuemin,Gu, Yonghong
experimental part, p. 1614 - 1620 (2011/04/22)
Treatment of various anilides with 1.5 equiv. of phenyliodine bis(trifluoroacetate) (PIFA) and 1.0 equiv. of BF3·OEt 2 in AcOH at room temperature afforded the corresponding para-acetoxylated products with high regioselectivity. In addition, this reaction could be expanded to the etherification of anilides. In the presence of 2.0 equiv. of PIFA and 2.0 equiv. of BF3·OEt2, the reaction of anilides with alcohols provided the corresponding para-etherified products in good yields. The Royal Society of Chemistry 2011.
Towards the synthesis of aminodibenzo[b,e][1,4]dioxin derivatives via cationic ruthenium complexes
Cambie, Richard C.,Clark, George R.,Coombe, Sheryl L.,Coulson, Sally A.,Rutledge, Peter S.,Woodgate, Paul D.
, p. 1 - 21 (2007/10/03)
Double nucleophilic aromatic substitution reactions between N-substituted (η6-1,2-dichlorobenzene)RuCp+ salts and substituted 1,2-benzenediols have been carried out under mild conditions to prepare N-substituted (η6-dibenzo[b,e][1,4]dioxin)ruthenium(II) complexes. The dibenzodioxin ligands were subsequently liberated by photolysis, with radiation from a sunlamp or from a medium pressure Hg lamp (300 nm).
Structure Determination of the Active Sulfhydryl Reagent in Gill Tissue of the Mushroom Agaricus bisporus
Mize, Patrick D.,Jeffs, Peter W.,Boekelheide, Kim
, p. 3540 - 3543 (2007/10/02)
The red pigment found in sporulating gill tissue of the mushroom Agaricus bisporus, which is a potent inhibitor of a number of enzymes containing sulfhydryl groups at their active sites, is shown to be 2-hydroxy-4-imino-2,5-cyclohexadienone (4).
