75070-85-8

Basic information

• Product Name: rhodium hydrido (PEt₃)3 complex
• Synonyms: rhodium hydrido (PEt₃)3 complex
• CAS NO: 75070-85-8
• Molecular Weight: 458.39
• Mol File: 75070-85-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: rhodium hydrido (PEt₃)3 complex(CAS DataBase Reference)
• NIST Chemistry Reference: rhodium hydrido (PEt₃)3 complex(75070-85-8)
• EPA Substance Registry System: rhodium hydrido (PEt₃)3 complex(75070-85-8)

Safety Data

• Hazardous Substances Data: 75070-85-8(Hazardous Substances Data)

Upstream product

• 485817-98-9 [Rh(F)(PEt₃)₃] 
• 789-25-3 HSiPh₃ 
• 71902-33-5 3,5-difluoropyridine 
• 372-18-9 1,3-Difluorobenzene 
• 372-38-3 1,3,5-trifluorobenzene 
• 653-34-9 2,3,4,5,6-pentafluorostyrene 
• 1231760-55-6 [Rh{B(pinacolato)₂}(PEt₃)₃] 
• 100-68-5 methyl-phenyl-thioether 
• 456-56-4 phenyl trifluoromethylsulfide 
• 129922-51-6 2-<(trifluoromethyl)thio>biphenyl 
• 177551-63-2 [1,1′-biphenyl]-4-yl(trifluoromethyl)sulfane 
• 352-68-1 4-trifluoromethylthiotoluene 
• 78914-94-0 4-methoxyphenyl trifluoromethylsulfide 
• 940-76-1 (4-fluorophenyl)(trifluoromethyl)thioether 

Downstream Products

• 677-21-4 1,1,1-trifluoropropylene 
• 674790-07-9 Rh{(E)-C(CF₃)=CHF}(PEt₃)₃ 
• 379-50-0 triphenylsilyl fluoride 
• 421-07-8 1,1,1-trifluoropropane 
• 77645-96-6 trans-[Rh(CO)(py)(PEt₃)2][BPh₄] 
• 77661-46-2 [RhH₂(OH)(P(C₂H₅)3)3] 
• 77661-49-5 [Rh-cis-H₂(PEt₃)3]BPh₄ 

Relevant articles and documents

C-H and C-F bond activation reactions of pentafluorostyrene at rhodium complexes

The rhodium(i) complexes [Rh(Bpin)(PEt3)3] (1), [Rh(H)(PEt3)3] (5) and [Rh(Me)(PEt3)3] (14) were employed in reactions with pentafluorostyrene affording coordination of the olefin and C-F o

Catalytic borylation of SCF3-functionalized arenes by rhodium(I) boryl complexes: Regioselective C-H activation at the ortho-position

An unprecedented reaction pathway for the borylation of SCF 3-containing arenes using [Rh(Bpin)(PEt3)3] (pin=pinacolato) is reported. Catalytic processes were developed and the functionalizations proceed under mild reaction conditions. The C-H activations occur with a unique regioselectivity for the position ortho to the SCF 3 group, which apparently serves as directing group. Borylated SCF3 compounds can serve as versatile building blocks. SCF 3 building blocks: A unique reaction route allows access to SCF 3-functionalized arenes, which are borylated at the ortho-position. The functionalization proceeds by C-H borylation with [Rh(Bpin)(PEt 3)3] (pin=pinacolato), and the SCF3 group likely serves as directing group. The generated borylated SCF3 compounds are versatile building blocks for further transformations.

Synthesis of rhodium(I) boryl complexes: Catalytic N-H activation of anilines and ammonia

The treatment of the rhodium methyl complex [Rh(Me)(PEt3) 3] (1) with diboranes B2[(OR)2]2 gave the 16-valence-electron rhodium(I) boryl complexes [Rh{B(OR) 2}(PEt3)3] [2: (OR)2 = pin = pinacolato, O2C2Me4; 3: (OR)2 = cat = catecholato, O2C6H4; 4: (OR)2 = O2C5H10]. The reactions of 2 and 4 with anilines yielded the amidoboranes HN[B(OR)2](R′) [6: B(OR) 2 = Bpin, R′ = C6F5; 7: B(OR)2 = Bpin, R′ = Ph; 8: B(OR)2 = BO2C5H 10, R′ = Ph] and the rhodium hydrido complex [Rh(H)(PEt 3)3] (5) by N-H activation. The addition of ammonia to 2 resulted in the generation of the amine HN(Bpin)2 (9) as well as 5. The amidoboranes 6, 7, and 9 can also be synthesized catalytically with turnover numbers of 10 for 9 and 8 for 6 and 7. Sixteen-electron RhI boryl complexes are synthesized and used for N-H bond activation reactions of anilines. The treatment of [Rh(Bpin)(PEt3)3] (HBpin = pinacolborane) with NH3 yields the diborylamine HN(Bpin)2. The stoichiometric conversion led to the development of a new catalytic process, and [Rh(Bpin)(PEt3)3] is used as a catalyst to convert NH3 and B2pin2 into HN(Bpin) 2 at room temperature. Copyright