7526-28-5Relevant academic research and scientific papers
Direct Aryloxylation/Alkyloxylation of Dialkyl Phosphonates for the Synthesis of Mixed Phosphonates
Huang, Hai,Denne, Johanna,Yang, Chou-Hsun,Wang, Haobin,Kang, Jun Yong
supporting information, p. 6624 - 6628 (2018/05/14)
A strategy for the direct functionalization strategy of inertial dialkyl phosphonates with hydroxy compounds to afford diverse mixed phosphonates with good yields and functional-group tolerance has been developed. Mechanistic investigations involving both NMR studies and DFT studies suggest that an unprecedented highly reactive PV species (phosphoryl pyridin-1-ium salt), a key intermediate for this new synthetic transformation, is generated in situ from dialkyl phosphonate in the presence of Tf2O/pyridine.
Kinetics of reactions of ethyl p-nitrophenyl ethylphosphonate with anionic nucleophiles in a detergentless microemulsion
Bel'skii,Valeeva
, p. 2236 - 2239 (2007/10/03)
The kinetics of reactions of ethyl p-nitrophenyl ethylphosphonate with anionic nucleophiles in a delergentless water - oil microemulsion, formed in the n-hexane - water - isopropyl alcohol system, was studied. The rate constants of the reactions in the microemulsion are higher than those in aqueous solutions and increase with increasing isopropyl alcohol : water ratio.
