75437-07-9

Basic information

• Product Name: Benzene, (4-methyl-1-pentenyl)-, (E)-
• CAS NO: 75437-07-9
• Molecular Formula: C12H16
• Molecular Weight: 160.259
• Mol File: 75437-07-9.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: Benzene, (4-methyl-1-pentenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4-methyl-1-pentenyl)-, (E)-(75437-07-9)
• EPA Substance Registry System: Benzene, (4-methyl-1-pentenyl)-, (E)-(75437-07-9)

Safety Data

• Hazardous Substances Data: 75437-07-9(Hazardous Substances Data)

Upstream product

• 16721-45-2 triphenyl(phenylmethylene)phosphorane 
• 590-86-3 isovaleraldehyde 
• 691-37-2 4-Methyl-1-pentene 
• 17763-67-6 Phenyl triflate 
• 920-39-8 isopropylmagnesium bromide 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 28322-40-9 isoamyltriphenylphosphonium bromide 
• 100-52-7 benzaldehyde 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 34041-44-6 1-phenylpropenyl-lithium 
• 75-26-3 isopropyl bromide 
• 625-81-0 diisopropyl zinc 
• 4392-24-9 Cinnamyl bromide 
• 1068-55-9 isopropylmagnesium chloride 

Downstream Products

• 7332-97-0 4-methyl-1-phenylpentane-1,2-dione 
• 7779-78-4 (±)-4-methyl-1-phenyl-2-pentanol 
• 65473-82-7 2-isobutyl-3-phenyloxirane 

Relevant articles and documents

Regioselective Deaminative Allylation of Aliphatic Amines via Dual Cobalt and Organophotoredox Catalysis

Despite the rapid progress in C-C bond-forming reactions using Katritzky salts, their deaminative allylation remains a challenge. Inspired by the metallaphotoredox-catalyzed allylic substitution regime, here, we report the deaminative allylation of Katritzky salts via cobalt/organophotoredox dual catalysis. This cross-electrophile coupling enables regioselective allylation using a variety of allylic esters, overcoming the substrate limitations of reported protocols. Mechanistic studies indicate the involvement of a π-allyl cobalt complex as a radicalophile that mediates C-C bond formation.

A photocatalyst-free photo-induced denitroalkylation of β-nitrostyrenes with 4-alkyl substituted Hantzsch esters at room temperature

A photocatalyst-free stereoselectively photo-induced strategy for the denitroalkylation of β-nitrostyrenes using 4-alkyl substituted Hantzsch esters as the alkyl source under xenon lamp irradiation is developed. The reaction proceeds at room temperature and affords the corresponding products in moderate to excellent yields. The oxidant di-t-butyl peroxide serves as an efficient radical initiator under irradiation of a Xenon lamp, initiating alkyl radicals from the 4-alkyl substituted Hantzsch esters.

Stereospecific Iron-Catalyzed Carbon(sp2)-Carbon(sp3) Cross-Coupling with Alkyllithium and Alkenyl Iodides

An efficient synthetic protocol involving iron-catalyzed cross-coupling reactions between organolithium compounds and alkenyl iodides as key coupling partners was achieved. More than 30 examples were obtained with moderate to good yields and high stereospecificity. Gram-scale and synthetic applications of this procedure are recorded herein to demonstrate its feasibility and potential utilization.