755-27-1

Upstream product

• 383-63-1 ethyl trifluoroacetate, 
• 423-39-2 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane 

Downstream Products

• 132182-92-4 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane 
• 375-17-7 nonafluorobutane 
• 76-05-1 trifluoroacetic acid 

Relevant academic research and scientific papers

Reductive alkylation of perfluorocarboxylic acid esters with CCl 3F or CCl4 and synthesis of higher linear perfluoroketones

Barbier-type reductive alkylation of perfluorocarboxylic acid esters (I) with CFCl3 and activated Al was successfully performed to give α,α-dichloroperfluoroketones (II). A similar reaction of CF 3COOEt with CCl4 and Al provided a convenient synthesis of CF3COCCl3. Ketones (II) were fluorinated further with SbF5 to form higher linear perfluoroketones (IX). An alternative approach to the synthesis of ketones (IX) was proposed by reductive perfluoroalkylation of esters (I) under the action of RFI and Al.

Functionally Substituted Organic Peroxides. XIX. Kinetics of the Reaction of Poly- and Perfluorinated Carbonyl Compounds with tert-Butyl Hydroperoxide

The kinetics of noncatalytic reaction of fluorinated aliphatic and aromatic aldehydes, alkyl, cycloalkyl, and aryl ketones, and β-ketoesters with tert-butyl hydroperoxide were studied by IR spectroscopy.