375-17-7Relevant articles and documents
Copper-mediated aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides at room temperature
Qi, Qingqing,Shen, Qilong,Lu, Long
supporting information; experimental part, p. 6548 - 6551 (2012/06/04)
A Cu-mediated ligandless aerobic fluoroalkylation of arylboronic acids under mild conditions is described for the first time. The reaction tolerates a wide range of functional groups, allowing for further transformation. Mechanistic studies suggest that [RfCu] is the active Cu species that forms the desired perfluoroalkylarenes and that [RfCu] is generated from [PhCu] by either an oxidative addition/reductive elimination mechanism or nucleophilic substitution via a halogen "ate" intermediate.
An improved procedure for the synthesis of perfluoroalkylacetylenes
Calleja-Rubio,Crette,Blancou
, p. 361 - 364 (2007/10/03)
A new and easy way to synthesize acetylene compounds is proposed. This synthesis is improved by including in one-pot, three reactions in a single step, with good yields. The reactants are commonly used compounds.
Synthese de 3-perfluoroalkylprop-1-enes RF-CH2-CH=CH2
Rubio,Blancou,Commeyras
, p. 171 - 175 (2007/10/03)
The reactions of perfluoroalkyl iodides with allylbromide or chloride, in the presence of solid potassium hydroxide KOH give 3-perfluoroalkylprop-1-enes RFCH2CH=CH2 in good yields under mild conditions. This reaction represents a synthetically viable and convenient route to such compounds.