762287-68-3

Upstream product

• 100-39-0 benzyl bromide 
• 819814-42-1 β-1-p-tolylthio-6-O-trityl-D-glucopyranose 
• 1152-39-2 p-methylphenyl 1-thio-β-D-glucopyranoside 
• 76-83-5 trityl chloride 
• 106-45-6 para-thiocresol 
• 604-69-3 β-D-glucose pentaacetate 
• 28244-94-2 p-tolyl-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 83-87-4 D-glucose pentaacetate 

Downstream Products

• 787623-80-7 p-methylphenyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside 
• 88567-49-1 6-O-acetyl-2,3,4-tri-O-benzyl-D-glucopyranose 
• 158021-47-7 (2S,3S,4R)-1-(α-D-glucopyranosyloxy)-2-hexacosanoylamino-3,4-octadecanediol 
• 10548-46-6 1,6-anhydro-2,3,4-tri-O-benzyl-β-D-glucopyranose 
• 1363157-76-9 p-methylphenyl 6-O-benzoyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside 
• 1234307-07-3 1-O-(2,3,4-tri-O-benzyl-6-sulfo-α-D-glucopyranosyl)propane-1,3-diol sodium salt 
• 1383449-95-3 p-tolyl 2,3,4-tri-O-benzyl-6-O-p-tosyl-1-thio-β-D-glucopyranoside 
• 762287-73-0 p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside 
• 479252-05-6 ((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol 

Relevant academic research and scientific papers

Co2(CO)6-propargyl cation mediates glycosylation reaction by using thioglycoside

We discovered that the cobalt-propargyl cation can mediate the glycosylation reaction by activating the thioglycoside donor. The glyco-oxacarbenium cation was formed by transferring the thio-aglycone to the cobalt-propargyl cation that was generated from the cobalt-propargylated acceptor in situ via the activating with Lewis acid. The reactivity of the donor (Armed or dis-armed) and the amount of the Lewis acid control the releasing rate of the cobalt-propargyl group.

THIOALDOHEXOSE DERIVATIVE AND METHOD FOR PRODUCING SAME

PROBLEM TO BE SOLVED: To provide novel synthesis methods and novel intermediates of 3-(6-deoxysulfoaldohexose)-1-propanol derivatives. SOLUTION: The present invention provides a thioaldohexose derivative represented by the formula (III) where R is an optionally substituted alkyl group or an optionally substituted aryl group, R21, R31 and R41 are the same or different to represent a protective group of a hydroxy group, and -OR61 is a leaving group. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPO&INPIT

HUMAN iNKT CELL ACTIVATION USING GLYCOLIPIDS

Glycosphingolipids (GSLs) compositions and methods for iNKT-independent induction of chemokines are disclosed.

HUMAN iNKT CELL ACTIVATION USING GLYCOLIPIDS WITH ALTERED GLYCOSYL GROUPS

Glycosphingolipids (GSLs) bearing α-glucose (α-Glc) that preferentially stimulate human invariant NKT (iNKT) cells are provided. GSLs with α-glucose (α-Glc) that exhibit stronger induction in humans (but weaker in mice) of cytokines and chemokines and exp

Selective electrochemical glycosylation by reactivity tuning

Electrochemical glycosylation of a selenoglycoside donor proceeds efficiently in an undivided cell in acetonitrile to yield β-glycosides. Measurement of cyclic voltammograms for a selection of seleno-, thio-, and O-glycosides indicates the dependence of o