76649-99-5Relevant articles and documents
STEREOSPECIFIC EPOXIDATION OF ANTHRACYCLINONES: A ROUTE TO 8(R)-METHOXYDAUNOMYCINONE
Penco, Sergio,Angelucci, Francesco,Ballabio, Marzia,Vigevani, Aristide,Arcamone, Federico
, p. 2253 - 2256 (2007/10/02)
Stereoselective epoxidation of 1, the 7,8-unsaturated derivative of daunomycinone, followed by trans opening of the epoxide 2, afforded 8(R)-methoxydaunomycinone 6a: its configuration at C-8 was determined by chemical correlations and PMR studies.