76711-42-7

Basic information

• Product Name: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene
• Synonyms: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene
• CAS NO: 76711-42-7
• Molecular Weight: 206.36
• Mol File: 76711-42-7.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene(76711-42-7)
• EPA Substance Registry System: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene(76711-42-7)

Safety Data

• Hazardous Substances Data: 76711-42-7(Hazardous Substances Data)

Upstream product

• 938-81-8 N-nitrosoacetanilide 
• 14839-81-7 4-methoxy-N-nitrosoacetanilide 
• 1068-69-5 Tris(trimethylsilyl)methane 
• 123-11-5 4-methoxy-benzaldehyde 
• 5926-35-2 chlorobis(trimethylsilyl)methane 
• 696-62-8 para-iodoanisole 
• 754-05-2 ethenyltrimethylsilane 
• 138351-84-5 1-(4-methoxyphenyl)-2-trimethylsilylethanol 
• 768-60-5 4-methoxyphenylacetylen 
• 3989-14-8 (4-methoxyphenylethynyl)trimethylsilane 
• 617-86-7 triethylsilane 
• 100-17-4 para-methoxynitrobenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 41309-43-7 (2-bromovinyl)trimethylsilane 

Downstream Products

• 22145-09-1 (1E,3E)-1,4-bis(4-methoxyphenyl)buta-1,3-diene 
• 89510-55-4 1-p-nitrophenyl-4-p-nitrophenylbuta-1E,3E-diene 
• 136795-71-6 (1E,3E)-1-(4-methoxyphenyl)-4-(4'-nitrophenyl)-1,3-butadiene 
• 4842-77-7 (2E,4E)-5-(4-methoxyphenyl)-1-phenylpenta-2,4-dien-1-one 
• 65682-02-2 (2E,4E)-1,6-diphenyl-2,4-hexadiene-1,6-dione 
• 1428963-19-2 (1E,3E)-1-(4-methoxyphenyl)-4-(3,5-difluorophenyl)-1,3-butadiene 
• 1104997-33-2 (E)-1-(4-methoxyphenyl)-3,3-diphenyl-1-propene 
• 501-36-0 (E)-5-[2-4-(hydroxyphenyl)ethenyl]-1,3-benzenediol 
• 22255-22-7 3,5,4'-trimethoxy-trans-stilbene 
• 5043-91-4 (E)-4-chloro-4'-methoxystilbene 
• 136618-41-2 E-2'-p-methoxystyryl iodide 

Relevant articles and documents

Asymmetric Hydrosilylation of β-Silyl Styrenes Catalyzed by a Chiral Palladium Complex

A palladium complex coordinated with a chiral SIPHOS ligand was evaluated as an efficient catalyst for asymmetric hydrosilylation of β-silyl styrenes with trichlorosilane and 23 1,2-bis(silyl) chiral compounds were produced. Good to excellent enantioselec

Synthesis of multinuclear Rh(I) complexes bearing triazolylidenes and their application in C-C and c-Si bond forming reactions

Multidentate carbene ligands are valuable frameworks for the preparation of carbene complexes displaying higher nuclearity. In the present work, we report the synthesis of a series of mono- to tetra-[Rh(COD)I] complexes (3a- d) supported by mesoionic triazol-5-ylidenes. The general synthetic procedure involves the one step reaction of the appropriate triazolium (2a-d) salt in the presence of KHMDS and stoiquiometric amounts of the rhodium(I) precursor. Treatment of complexes 3a-d with an excess of carbon monoxide allows for the quantitative preparation of complexes 4a-d featuring a [Rh(CO)2I] fragment used for the detemination of the donor properties of the new triazolylidene ligands. All complexes have been fully characterized by means of 1H and 13C NMR spectroscopy, melting point, elemental analysis, and in the case of complex 3a, by X-ray crystallography. Comparison of the catalytic activity of the new rhodium complexes in C-C and C-Si bond forming processes demonstrate the enhanced performance of the tetranuclear species suggesting the possibility of strong cooperative effects in these multinuclear complexes.

Iron-Catalyzed Cross-Coupling of Bis-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and mechanistic investigations

Various substituted bis-(aryl)manganese species were prepared from aryl bromides by one-pot insertion of magnesium turnings in the presence of LiCl and in situ trans-metalation with MnCl2 in THF at ?5 ?C within 2 h. These bis-(aryl)manganese reagents undergo smooth iron-catalyzed cross-couplings using 10 mol% Fe(acac)3 with various functionalized alkenyl iodides and bromides in 1 h at 25 ?C. The aryl-alkenyl cross-coupling reaction mechanism was thoroughly investigated through paramagnetic 1H-NMR, which identified the key role of tris-coordinated ate-iron(II) species in the catalytic process.