7698-05-7Relevant articles and documents
Smits, A.,Muller, G. J.
, p. 804 - 804 (1937)
Phillips, C. S. E.
, p. 518 - 519 (1951)
Kinetic study of the reaction of chlorine atoms with chloromethane in the gas phase
Sarzyński, Dariusz,Gola, Agnieszka A.,Dry?, Andrzej,Jodkowski, Jerzy T.
, p. 138 - 142 (2009)
The kinetics of the gas phase reactions of chlorine atoms with chloromethane and D-chloromethane CD3Cl was studied experimentally. The relative rate method was applied using Cl + CH3Br as the reference reaction. The rate constants fo
H/D isotope effects on formation and photodissociation of HKrCl in solid Kr
Khriachtchev, Leonid
, p. 6403 - 6410 (2003)
The H/D isotope effects on formation and photodissociation of HKrCl in solid Kr were investigated. The formation kinetics of HKrCl and DKrCl reveals the isotope effect on thermally activated mobility of atomic hydrogen. Thus, the difference between the H and D mobilities allowed to show that a reaction of D atoms with HKrCl was taking place. Thus, the HKrCl and DKrCl photodecomposition rates were compared.
Brown, H. C.,Groot, C.
, p. 2223 - 2224 (1942)
Hoegfeldt, E.,Bigeleisen, J.
, p. 15 - 20 (1960)
Kinetics of the Cl-H2 system. II. Abstraction vs exchange in D+HCl
Miller, John C.,Gordon, Robert J.
, p. 3713 - 3720 (1983)
The gas phase reaction of D with HCl was studied at room temperature by the method of flash photolysis, with resonance fluorescence detection of D, H, and Cl atoms.The D and Cl atoms were observed to decay exponentially, whereas no H atom signal the excha
Kinetics of the Cl-H2 system. III. The deuterium isotope effect in Cl + H2
Miller, John C.,Gordon, Robert J.
, p. 1252 - 1258 (1983)
The rate constant for the reaction Cl+D2 was measured over the temperature range 200-500 K, using the flash photolysis-resonance fluorescence technique.These data, together with previous measurements for Cl+H2, are compared with the isotope effect measured by Persky and Klein in a static bulb.Over the range 295-500 K, our data are in excellent agreement with their results.At lower temperatures, the Cl+D2 rate constant displays an anomalous non-Arrhenius curvature.A mechanism involving the reaction of Cl atoms with vibrationally excited D2 is proposed to explain this effect.
Kinetic study of the reaction of chlorine atoms with dichloromethane and D-dichloromethane in the gas phase
Sarzyński, Dariusz,Gola, Agnieszka A.,Brudnik, Katarzyna,Jodkowski, Jerzy T.
, p. 220 - 225 (2011/11/28)
The kinetics of the gas-phase reactions of chlorine atoms with dichloromethane (CH2Cl2) and D-dichloromethane (CD 2Cl2) was studied using the relative rate method with Cl + CH3Br as the reference reaction. The rate constants for H-abstraction from CH2Cl2 (kH) and D-abstraction from CD2Cl2 (kD) were measured in the temperature range of 298-527 K and at a total pressure of 100 Torr using N2 as a diluent. The temperature dependencies of the rate constants (with the 2σ error limits) are described by the expressions: kH = (8.69 ± 0.82) × 10-12 × exp(-955 ± 20/T) and kD = (6.98 ± 0.91) × 10-12 × exp(-1285 ± 25/T) cm3 molecule-1 s-1. The kinetic isotope effect, described by the ratio kH/kD, was found of 3.8 ± 0.2 at room temperature.
