76999-62-7Relevant articles and documents
NOVEL PREPARATION OF 1,3-PROPANEDIYL BIS: A ONE-STEP NUCLEOPHILIC SYNTHESIS OF SYMMETRIC 1,3-DIGLYCERIDES
Brown, Alan B.,Whitlock, Howard W.
, p. 3497 - 3508 (2007/10/02)
The title compound 1 was prepared by treatment of epibromohydrin with carboxylic acid 2 in the presence of tertiary amine; the reaction is a new nucleophilic synthesis of symmetric 1,3-diglycerides.
AN ASYMMETRIC SYNTHESIS OF GLYCEROL DERIVATIVES BY THE ENANTIOSELECTIVE ACYLATION OF PROCHIRAL GLYCEROL
Ichikawa, Junji,Asami, Masatoshi,Mukaiyama, Teruaki
, p. 949 - 952 (2007/10/02)
Optically active glycerol derivatives are obtained in up to 84percent e.e. by the selective acylation of the tin(II) alkoxides generated from 2-O-arylsulfonylglycerols and 1,1'-dimethylstannocene or (mehthylcyclopentadienyl)tin(II) chloride by the use of a chiral diamine derived from (S)-proline as a ligand.