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[2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium is a chemical compound belonging to the diazeniumdiolate class, characterized by a unique N2O2 four-membered ring derived from the conversion of nitric oxide to its anion. It features a 2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene group, which includes a ketone and an aromatic ring with three methoxy substituents, giving it distinct chemical properties and potential applications.

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  • 7702-09-2 Structure
  • Basic information

    1. Product Name: [2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium
    2. Synonyms:
    3. CAS NO:7702-09-2
    4. Molecular Formula: C11H12N2O4
    5. Molecular Weight: 237.2314
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 7702-09-2.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium(CAS DataBase Reference)
    10. NIST Chemistry Reference: [2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium(7702-09-2)
    11. EPA Substance Registry System: [2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium(7702-09-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 7702-09-2(Hazardous Substances Data)

7702-09-2 Usage

Uses

Used in Pharmaceutical Industry:
[2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium is used as a pharmaceutical compound for its potential therapeutic applications. [2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium's unique structure and functional groups may allow it to interact with biological targets, such as enzymes or receptors, in ways that could lead to the development of new drugs for various diseases.
Used in Chemical Research:
In the field of chemical research, [2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium serves as a valuable compound for studying the properties and reactivity of diazeniumdiolate derivatives. Its unique structure can provide insights into the behavior of similar compounds and contribute to the advancement of chemical knowledge.
Used in Material Science:
[2-oxo-2-(3,4,5-trimethoxyphenyl)ethylidene]diazenium may also find applications in material science, where its distinct chemical properties could be utilized in the development of new materials with specific characteristics, such as improved stability, reactivity, or selectivity in various chemical processes.

Check Digit Verification of cas no

The CAS Registry Mumber 7702-09-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,7,0 and 2 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 7702-09:
(6*7)+(5*7)+(4*0)+(3*2)+(2*0)+(1*9)=92
92 % 10 = 2
So 7702-09-2 is a valid CAS Registry Number.

7702-09-2Relevant articles and documents

Preparation method for 2-diazonium-1-alkyl ketone compound

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Paragraph 0054; 0055; 0056; 0057; 0058, (2017/06/02)

The invention provides a preparation method for a 2-diazonium-1-alkyl ketone compound. The preparation method is characterized in that a beta-dicarbonyl compound, p-toluenesulfonyl azide and methylamine are taken as raw materials, and a catalyst and alkali are not needed under a room-temperature condition, so that the 2-diazonium-1-alkyl ketone compound can be quickly and efficiently generated. Compared with the prior art, the preparation method is safe, simple and convenient to operate, and avoids a diazotization step which is dangerous to operate. The preparation method is gentle in reaction condition, is quick and efficient, and provides a brand-new and more convenient method for quickly and efficiently preparing an alpha-diazonium-alkyl ketone compound, and the method can be applied to the fields such as the chemical pharmaceuticals, the biological field and the material field.

Tandem Synthesis of α-Diazoketones from 1,3-Diketones

Zhang, Jianlan,Chen, Wenwen,Huang, Dayun,Zeng, Xiaobao,Wang, Xinyan,Hu, Yuefei

, p. 9171 - 9174 (2017/09/11)

A highly efficient synthesis of α-diazoketone was achieved by simply stirring the mixture of 1,3-diketone, TsN3, and MeNH2 in EtOH. It was a tandem reaction including a novel primary amine-catalyzed Regitz diazo transfer of 1,3-diket

An efficient PEG-400 mediated catalyst free green synthesis of 2-amino-thiazoles from α-diazoketones and thiourea

Babu, B Hari,Vijay,Murali Krishna, K Bala,Sharmila,Ramana, M Baby

, p. 1475 - 1478 (2016/09/19)

A simple and efficient method has been developed for the synthesis of 2-aminothiazoles from α-diazoketones using PEG-400 solvent system. This novel synthetic approach involves the reaction between thiourea and α-diazoketones in PEG-400 at 100 °C to yield the corresponding 2-aminothiazoles in good yields. The method is simple, rapid and generates thiazole derivatives in excellent yields without the use of any catalysts. This green protocol can be utilized for fast synthesis of various 2-aminothiazoles in good yields. [Figure not available: see fulltext.]

Safe and reliable synthesis of diazoketones and quinoxalines in a continuous flow reactor

Martin, Laetitia J.,Marzinzik, Andreas L.,Ley, Steven V.,Baxendale, Ian R.

supporting information; experimental part, p. 320 - 323 (2011/03/23)

A flow method for the synthesis of aliphatic and aromatic diazoketones from acyl chloride precursors has been developed and used to prepare quinoxalines in a multistep sequence without isolation of the potentially explosive diazoketone. The protocol showcases an efficient in-line purification using supported scavengers with time-saving and safety benefits and in particular a reduction in the operator's exposure to carcinogenic phenylenediamines.

First example of the coupling of α-diazoketones with thiourea: a novel route for the synthesis of 2-aminothiazoles

Yadav,Reddy, B.V. Subba,Rao, Y. Gopala,Narsaiah

, p. 2381 - 2383 (2008/09/18)

α-Diazoketones undergo smooth coupling with thiourea in the presence of 10 mol % of copper(II) triflate to produce the corresponding 2-aminothiazoles in excellent yields with high selectivity. The use of copper(II) triflate makes this method simple, convenient and practical. This method works well with both aryl and alkyl diazoketones to furnish a wide range of 2-aminothiazoles.

Aracyl triflates as derivatizing agents for biological betaines

Happer, D. Alan R.,Hayman, Colin M.,Storer, Malina K.,Lever, Michael

, p. 467 - 472 (2007/10/03)

Several trifluoromethanesulfonates of general structure ArCOCH 2OTf were prepared and their suitability for use as derivatizing agents for the HPLC analysis of betaines was assessed. Four of them (Ar=2′-naphthyl, 2′-fluorenyl, 6′-methoxynaphtha

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