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• 20333-40-8 dibutyl diselenide 
• 100-52-7 benzaldehyde 
• 93-97-0 benzoic acid anhydride 
• 70-11-1 α-bromoacetophenone 

Relevant academic research and scientific papers

Facile formation of samarium (III) selenolates from potassium iodide catalyzed reaction of samarium metal and diselenides, and their application in synthesis of selenoesters

Samarium metal reacts with diselenides in the presence of a catalytic amount of potassium iodide to generate samarium(III) selenolates. Samarium (III) selenolates thus formed in situ, react with acid chlorides to give selenoesters in moderate yields.

Synthesis of selenol esters via the reaction of acyl chlorides with diselenides in the presence of Zn dust catalyzed by CoCl2·6H2O

A practical and efficient approach for the synthesis of selenol and thiol esters is described via the reaction of acyl chlorides with diselenides or disulfides in the presence of Zn dust catalyzed by inexpensive CoCl2·6H2O This proto

Iron(III)-catalyzed synthesis of selenoesters from α-amino carbonyl derivatives at room temperature

An Fe(III)-catalyzed efficient method has been developed for the synthesis of selenoester derivatives in high yields through the coupling of α-amino carbonyl/glycine derivatives and diselenides under ambient air. A library of benzoselenoate derivatives having a variety of substituents has been synthesized. A plausible reaction pathway has been predicted. Experimental results suggest that the reaction proceeds through a radical pathway. Operational simplicity, compatibility with various α-amino carbonyls and diselenides, high yields, fast reaction and mild reaction conditions are the notable advantages of this procedure. We have also shown the practical application of the synthesized selenoesters which is useful to generate peptide bonds in biological sciences.

Iron-catalyzed synthesis of selenoesters from diselenides and acyl chlorides or acid anhydrides in the presence of magnesium dust

A novel and efficient synthetic methodology for the iron-catalyzed preparation of selenoesters by the reaction of diselenides with acyl chlorides or acid anhydrides has been developed. In the presence of magnesium dust, iron catalyzes the cleavage of the

Water accelerated Sm/TMSC1 reductive cleavage of the Se-Se bond: Synthesis of selenoesters and selenoformates

The reduction of diselenides by the Sm/TMSC1/H2O system led to selenide anions. These 'living' species reacted smoothly with acid chlorides, acid anhydrides and methyl chloroformate respectively to afford the desired selenoesters and selenoform

Low-valent titanium induced reductive coupling of diaryl diselenides with acid chlorides or acid anhydrides: facile synthesis of selenoestersf

Selenoesters have been prepared in good yieFd b'yreaction of diaryl diselenides with acid chlorides or acid anhydrides induced by the TiCI4-Sm-THF system under mild reaction conditions.

Mild transformation of telluro and seleno esters into carboxylic acid and esters

Te-Butyl Telluroesters and Se-Butyl Selenoesters are hydrolyzed to carboxylic acids under very mild conditions by reaction with copper(II) chloride dihydrate. When the reaction is performed in ethanol or methanol, using anhydrous copper(II) chloride a transesterification occurred leading to the oxygenated esters in good yield.

Synthesis Utilizing Reducing Ability of Carbon Monoxide: A New Method for Selective Synthesis of Diorganyl Selenides and Diselenides Using a Selenium-Carbon Monoxide-Water Reaction System

A new approach to the synthesis of diorganyl selenides and diselenides is described.Selective generation of tertiary amine salts of hydrogen selenide (->*+>) and hydrogen diselenide (->*+>) ha