77357-46-1Relevant academic research and scientific papers
Formal total synthesis of kendomycin by way of alkyne metathesis/gold catalysis
Hoffmeister, Laura,Persich, Peter,Fuerstner, Alois
supporting information, p. 4396 - 4402 (2014/05/06)
In an attempt to study the ability of the latest generation of alkyne metathesis catalysts to process sterically hindered substrates, two different routes to the bacterial metabolite kendomycin (1) were explored. Whereas the cyclization of the overcrowded
Formal synthesis of (-)-kendomycin featuring a prins-cyclization to construct the macrocycle
Bahnck, Kevin B.,Rychnovsky, Scott D.
supporting information; experimental part, p. 13177 - 13181 (2009/03/12)
The kendomycin skeleton was prepared by a highly convergent strategy in which the benzofuran fragment and the acyclic iodide fragment were prepared by standard methods and joined using a Suzuki coupling. The distinctive reaction in our approach was an int
Amine Addition to Unsymmetrical Benzoquinones
Luly, Jay R.,Rapoport, Henry
, p. 2745 - 2752 (2007/10/02)
New routes to 2-methoxy-3-methyl-1,4-benzoquinone and 4-methoxy-3-methyl-1,2-benzoquinone have been developed.Both quinones undergo highly regioselective oxidative amination with pyrrolidine and copper acetate, yielding aminoquinones related to the mitomy
