77785-94-5

Basic information

• Product Name: Benzaldehyde, 4-(2-propenyl)- (9CI)
• Synonyms: Benzaldehyde, 4-(2-propenyl)- (9CI);4-allylbenzaldehyde
• CAS NO: 77785-94-5
• Molecular Formula: C₁₀H₁₀O
• Molecular Weight: 146.1858
• Product Categories: ALDEHYDE
• Mol File: 77785-94-5.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzaldehyde, 4-(2-propenyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 4-(2-propenyl)- (9CI)(77785-94-5)
• EPA Substance Registry System: Benzaldehyde, 4-(2-propenyl)- (9CI)(77785-94-5)

Safety Data

• Hazardous Substances Data: 77785-94-5(Hazardous Substances Data)

Usage

General Description

Benzaldehyde, 4-(2-propenyl)- (9CI) is a chemical compound with the molecular formula C9H10O. It is a colorless liquid that is commonly used in the production of flavorings, perfumes, and dyes. It is also found naturally in certain foods, such as almonds, cherries, and peaches. In addition to its uses in the food and fragrance industries, benzaldehyde, 4-(2-propenyl)- (9CI) is also utilized in the manufacture of pharmaceuticals and as a precursor for various chemical syntheses. It is important to handle this compound with caution, as it can be irritating to the skin, eyes, and respiratory system if not used properly.

Upstream product

• 122-51-0 orthoformic acid triethyl ester 
• 87199-17-5 4-formylphenylboronic acid, 
• 107-18-6 allyl alcohol 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 45966-51-6 1-allyl-4-vinylbenzene 
• 3959-07-7 4-Bromobenzylamine 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 1395346-57-2 C₁₆H₂₅N 
• 307537-99-1 2-(4-allylphenyl)-5,5-dimethyl-1,3-dioxane 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1122-91-4 4-bromo-benzaldehyde 
• 556-56-9 allyl iodid 
• 100-52-7 benzaldehyde 
• 1184723-05-4 2-(4-allylphenyl)-1,3-dioxolane 

Downstream Products

• 753460-14-9 5-(4-allylphenyl)dipyrromethane 
• 51980-05-3 4-allylbenzonitrile 
• 4489-11-6 4-prop-2-enylbenzyl alcohol 
• 1589528-81-3 (E)-4-(4-methyl-4-nitro-5-oxo-5-phenylpent-1-en-1-yl)benzaldehyde 
• 1440773-79-4 (1E,2S)-4-(3-(2-acetyl-1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)prop-1-en-1-yl)benzaldehyde 
• 1176891-04-5 (E)-methyl 3-(4-formylphenyl)allyl(tosyl)carbamate 

Relevant articles and documents

Nitrile Synthesis by Aerobic Oxidation of Primary Amines and in situ Generated Imines from Aldehydes and Ammonium Salt with Grubbs Catalyst

Herein, a Grubbs-catalyzed route for the synthesis of nitriles via the aerobic oxidation of primary amines is reported. This reaction accommodates a variety of substrates, including simple primary amines, sterically hindered β,β-disubstituted amines, allylamine, benzylamines, and α-amino esters. Reaction compatibility with various functionalities is also noted, particularly with alkenes, alkynes, halogens, esters, silyl ethers, and free hydroxyl groups. The nitriles were also synthesized via the oxidation of imines generated from aldehydes and NH4OAc in situ. (Figure presented.).

Mild oxidation of benzylic amines into aldehydes using an oxidative Polonovski-like process

A chemoselective and environmentally benign oxidation of benzylic amines into aldehydes mediated by a hypervalent iodine reagent has been developed. This mild oxidative version of the Polonovski process may be selectively carried out in the presence of several functionalities including a free alcohol and provides new synthetic opportunities as a masked aldehyde segment. Georg Thieme Verlag Stuttgart · New York.

Synthesis of porphyrins designed for attachment to electroactive surfaces via one or more carbon tethers

Porphyrin compounds having a surface attachment group coupled thereto at the 5 position are described. The surface attachment group has the formula: wherein R is —CHCH2 or —CCH and Ar is an aromatic group. Methods and intermediates useful for m