7790-46-7Relevant academic research and scientific papers
Platinum Iodide Compounds
Kukushkin,Pakhomova
, p. 69 - 70 (2008/10/08)
New and improved methods for synthesis of PtI4, PtI3, and PtI2 are proposed. The [Pt(DMSO)I2]2 complex is synthesized by reacting PtI2 and [Pt(DMSO)2Cl2] with KI.
On Hexaiodoplatinates(IV) M2PtI6 (M = K, Rb, Cs, NH4, Tl) - Preparation, Properties and Structural Data
Thiele, Gerhard,Mrozek, Christian,Kammerer, Dieter,Wittmann, Kurt
, p. 905 - 910 (2007/10/02)
Crystals of hexaiodoplatinates(IV) M2PtI6 (M = K, Rb, Cs, NH4, Ti) have been obtained by heating PtI4 or H2PtCl6 in highly concentrated aqueous solutions of MI in the presence of small amounts of HI and I2 in an ampoule for 24 h at 160 deg C.The structural parameters were determined from single crystal data.In water less soluble compounds with M = Rb, Cs, NH4 show the cubic K2PtCl6 structure, whereas the easily water soluble salts with M = K, Tl both crystallize in a tetragonally distorted version of this structure type. - Key words: Iodoplatinates, Crystal Structure, Hexaiodoplatinates(IV)
