78002-37-6Relevant articles and documents
Synthesis and spectral characterization of zinc(II) and cadmium(II) complexes of acetone-N(4)-phenylsemicarbazone: Crystal structures of acetone-N(4)-phenylsemicarbazone and a cadmium(II) complex
Siji,Sudarsanakumar,Suma
, p. 2035 - 2040 (2010)
Seven Zn(II) and Cd(II) complexes of ON donor acetone-N(4)- phenylsemicarbazone (HL) have been synthesized and physico-chemically characterized by partial elemental analyses, molar conductance measurements, infrared, electronic and 1H NMR spect
Anodic cleavage of several ketone N-phenylsemicarbazones into methyl N-phenylcarbamate and the corresponding dimethyl acetals
Nishikawa, Shinnosuke,Yamamori, Haruki,Ohashi, Kousuke,Okimoto, Mitsuhiro,Hoshi, Masayuki,Yoshida, Takashi
, p. 1766 - 1771 (2013/05/21)
Several ketone N-phenylsemicarbazones were electrooxidized in the presence of potassium iodide and a base using methanol as the solvent to give nearly commensurate amounts of methyl N-phenylcarbamate and the corresponding dimethyl acetals. Continuous evolution of gaseous nitrogen was observed from the anolyte during the electrooxidation. The reactions were carried out under very mild reaction conditions and are presumed to proceed through a four-electron oxidation process, in which the iodide ion plays an important role as an electron carrier.