782-23-0Relevant articles and documents
Weizmann et al.
, p. 2325 (1951)
ORTHO-SUBSTITUTED TRIPTYCENE-BASED DIAMINES, MONOMERS, AND POLYMERS, METHODS OF MAKING AND USES THEREOF
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Paragraph 0049, (2019/03/08)
Described herein are ortho-dimethyl-substituted and tetramethyi-substituted triptycene-containing diamine monomers and microporous triptycene-based poiyimides and poiyamides, and methods of making the monomers and polymers.
Two-photon absorption properties of 2,6-bis(styryl)anthracene derivatives: Effects of donor-acceptor substituents and the π center
Yang, Wen Jun,Kim, Dae Young,Jeong, Mi-Yun,Kim, Hwan Myung,Lee, Yun Kyoung,Fang, Xingzhong,Jeon, Seung-Joon,Cho, Bong Rae
, p. 4191 - 4198 (2007/10/03)
A series of 2,6- and 2,7-bis-(styryl)anthracene derivatives with the donors at the styryl group and acceptors at the 9,10-positions have been synthesized, and their two-photon cross sections (φδmax) were determined. These compounds exhibit a peak two-photon absorptivity (δmax) in the range of 700-2500 GM at 780-1030 nm. Values of λmax and Stokes shifts increase as the acceptor is changed to a stronger one. There is also a parallel increase in λmax (2) and δmax with the same variation of the chromophore structure. Both λmax(2) and φδmax have been optimized by introducing donor-substituted styryl groups at the 2,6-positions and p-cyanophenyl groups at the 9,10-positions, respectively. The effect of a π center on the two-photon absorption properties has been assessed by comparing the existing data for a variety of D-π-D derivatives.
Dealkylation of tert-butylcalix[n]arenes in toluene: Formation of 2,6 and 2,7-dimethylanthracenes
Yao, Benjamin,Bassus, Jacques,Lamartine, Roger
, p. 165 - 167 (2007/10/03)
An eutectic mixture of 2.6-dimethylanthracene VI and 2,7-dimethylantracene VII was formed during deterbutylation reaction of calix[n]arenes in toluene with aluminium chloride as catalyst. Using the deterbutylation of p-tert- butylcalix |4]arene I as a model we propose a mechanism of their formation. Springen Verlag Iberica 1997.