78315-32-9Relevant academic research and scientific papers
Cobalt-Catalyzed Hydroxyperfluoroalkylation of Alkenes with Perfluoroalkyl Bromides and Atmospheric Oxygen
Sun, Qilin,Pang, Liangzhi,Mao, Shuxian,Fan, Wu,Zhou, Yuyi,Xu, Jing,Li, Suhua,Li, Qiankun
, p. 1353 - 1364 (2021/12/02)
A mild and efficient method for the cobalt-catalyzed hydroxyperfluoroalkylation of alkenes has been developed. This method demonstrated broad substrate scope, good yields, and mild conditions with the tolerance of mono-, di-, and trisubstituted alkenes including both styrenes and non-activated aliphatic olefins. This strategy offered a valuable solution for rapid and efficient construction of β-perfluoroalkyl alcohols using widely available and inexpensive perfluoroalkyl bromides and atmospheric oxygen.
Reactivity of 1-bromo-1,1-difluoro-2-alkenes: Synthesis of 1,1 -difluoroolefins
Tellier, Frederique,Duffault, Jean-Marc,Baudry, Monique,Sauvetre, Raymond
, p. 133 - 139 (2007/10/03)
The treatment of 1-bromo-1,1-difluoro-2-alkenes with organometallic reagents in the presence of copper and lithium salts leads to 1,1-difluoroolefins.
Electroreductive coupling of halofluoro compounds with aldehydes
Shono,Kise,Oka
, p. 6567 - 6570 (2007/10/02)
Electroreductive intermolecular coupling of halofluoro compounds such as 1,1,1-trichloro-2,2,2-trifluoroethane, methyl chlorodifluoroacetate, and perfluoroalkyl halides with aldehydes took place effectively in the presence of chlorotrimethylsilane and one of the coupling products, 2,2-dichloro-3,3,3-trifluoro-1-phenyl-1-propranol, was selectively convertible to a variety of compounds with using the electroreduction as a key reaction.
Reaction de CF2=CH2 avec les organolithiens . Une nouvelle preparation du difluorovinyllithium
Sauvetre, R.,Normant, J. F.
, p. 957 - 958 (2007/10/02)
2,2-Difluorovinyllithium has been prepared in quantitative yield from CF2=CH2 and sec.butyllithium at low temperature.Reaction of 2,2-difluorovinyllithium with carbonyl groups gives the corresponding alcohols.
