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78560-45-9

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Product FOB Price Min.Order Supply Ability Supplier
SAGECHEM/ (1H,1H,2H,2H-Tridecafluorooctyl)trichlorosilane /Manufacturer in China
Cas No: 78560-45-9
No Data No Data Metric Ton/Day SAGECHEM LIMITED Contact Supplier
1H,1H,2H,2H-perfluorooctyltrichlorosilane
Cas No: 78560-45-9
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Trichloro(1H,1H,2H,2H-tridecafluoro-n-octyl)silane
Cas No: 78560-45-9
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Factory Supply Trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
Cas No: 78560-45-9
No Data 1 1 Ality Chemical Corporation Contact Supplier
trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
Cas No: 78560-45-9
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
78560-45-9 1H,1H,2H,2H-PERFLUOROOCTYLTRICHLOROSILANE
Cas No: 78560-45-9
USD $ 8900.0-8900.0 / Gram 1 Gram 200 Gram/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Top Purity CAS 78560-45-9 with fast shipping
Cas No: 78560-45-9
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
BLOOM TECH Advanced API/Technology support Trichloro(1H,1H,2H,2H-tridecafluoro-n-octyl)silane , CAS 78560-45-9
Cas No: 78560-45-9
No Data 1 Gram 3 Metric Ton/Month Shaanxi BLOOM TECH Co.,Ltd Contact Supplier
Silane,trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)- 78560-45-9
Cas No: 78560-45-9
No Data 1 Kilogram 10000 Metric Ton/Month Shanghai Upbio Tech Co.,Ltd Contact Supplier
(Tridecafluoro-1,1,2,2-tetrahydrooctyl)-1-trichlorosilane
Cas No: 78560-45-9
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier

78560-45-9 Usage

Chemical Properties

colourless liquid

Uses

1H,1H,2H,2H-Perfluorooctyltrichlorosilane is used in the silanization of silicon wafer. Self assembled monolayers treated with this, acts as an anti adhesive layer and release of cured poly(dimethyl siloxanes). It is also used to fabricate chemical surface patterns of self assembled monolayers.

General Description

Trichloro(1H,1H,2H,2H-perfluorooctyl)silane (PFOCTS) is a chlorosilane that forms a self-assembled monolayer (SAM) on a variety of substrates. It is majorly used to modify the surface with superhydrophobic properties. It is a biocompatible polymer with low surface energy. PFOCTS exhibits anti-fouling properties with high wettability which facilitates the release of different composites from the mold.
InChI:InChI=1/C8H4Cl3F13Si/c9-25(10,11)2-1-3(12,13)4(14,15)5(16,17)6(18,19)7(20,21)8(22,23)24/h1-2H2

78560-45-9 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (L16606)  1H,1H,2H,2H-Perfluorooctyltrichlorosilane, 97%    78560-45-9 10g 884.0CNY Detail
Alfa Aesar (L16606)  1H,1H,2H,2H-Perfluorooctyltrichlorosilane, 97%    78560-45-9 50g 3615.0CNY Detail
Aldrich (448931)  Trichloro(1H,1H,2H,2H-perfluorooctyl)silane  97% 78560-45-9 448931-10G 973.44CNY Detail

78560-45-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Trichloro(1H,1H,2H,2H-tridecafluoro-n-octyl)silane

1.2 Other means of identification

Product number -
Other names trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:78560-45-9 SDS

78560-45-9Synthetic route

Pt(0)-divinyltetramethyidisiloxane

Pt(0)-divinyltetramethyidisiloxane

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene
25291-17-2

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

Conditions
ConditionsYield
With trichlorosilane In 5,5-dimethyl-1,3-cyclohexadiene99%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene
25291-17-2

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate; trichlorosilane at 100℃; for 70h;98%
With dihydrogen hexachloroplatinate; trichlorosilane In isopropyl alcohol at 100℃;83%
With trichlorosilane; chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex at 60℃; for 4h;80%
With dihydrogen hexachloroplatinate; trichlorosilane In isopropyl alcohol at 100℃; for 18h;79%
With trichlorosilane; platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane In xylene at 86 - 126℃; under 760.051 - 5625.56 Torr; for 4.5 - 10.5h; Product distribution / selectivity;2.6%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene
25291-17-2

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene

trichlorosilane
10025-78-2

trichlorosilane

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

Conditions
ConditionsYield
platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In xylene at 110℃; under 18751.9 Torr; for 192h; Industry scale;
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

(1H,1H,2H,2H-tridecafluoro-octyl)trifluorosilane
157333-81-8

(1H,1H,2H,2H-tridecafluoro-octyl)trifluorosilane

Conditions
ConditionsYield
With hydrogen fluoride In ethanol at 0℃;99%
With hydrogen fluoride In diethyl ether; ethanol Ambient temperature; Yield given;
1,3,5,7,9,11,14-heptaisobutyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol
307531-92-6

1,3,5,7,9,11,14-heptaisobutyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

heptaisobutyl(tridecafluoro-1,1,2,2-tetrahydrooctyl)-T8-silsesquioxane

heptaisobutyl(tridecafluoro-1,1,2,2-tetrahydrooctyl)-T8-silsesquioxane

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;98%
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

1,3,5,7,9,11,14-heptacyclopentyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol
183387-28-2

1,3,5,7,9,11,14-heptacyclopentyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol

heptacyclopentyl(3,3,3-tridecafluoro-1,1,2,2-tetrahydrooctyl)-T8-silsesquioxane

heptacyclopentyl(3,3,3-tridecafluoro-1,1,2,2-tetrahydrooctyl)-T8-silsesquioxane

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 0.416667h; Inert atmosphere;92%
C10H10F8O3
66818-53-9

C10H10F8O3

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

C38H31F37O9Si

C38H31F37O9Si

Conditions
ConditionsYield
at 0℃; for 7h; Inert atmosphere; Neat (no solvent);90%
allyl bromide
106-95-6

allyl bromide

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

1H,1H,2H,2H-perfluorooctyltriallylsilane
193828-95-4

1H,1H,2H,2H-perfluorooctyltriallylsilane

Conditions
ConditionsYield
Stage #1: allyl bromide With magnesium In diethyl ether at 0 - 5℃; for 2h;
Stage #2: (tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane In diethyl ether for 24h; Heating;
82%
hepta(3,3,3-trifluoropropyl)tricycloheptasiloxane trisodium silanolate

hepta(3,3,3-trifluoropropyl)tricycloheptasiloxane trisodium silanolate

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

tridecafluoro-1,1,2,2-tetrahydrooctylhepta(3,3,3-trifluoropropyl)-T8-silsesquioxane
1003025-04-4

tridecafluoro-1,1,2,2-tetrahydrooctylhepta(3,3,3-trifluoropropyl)-T8-silsesquioxane

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 3h;82%
With triethylamine In tetrahydrofuran Inert atmosphere;
sodium methylate
124-41-4

sodium methylate

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

(1H,1H,2H,2H-tridecafluorooctyl)trimethoxysilane

(1H,1H,2H,2H-tridecafluorooctyl)trimethoxysilane

Conditions
ConditionsYield
In methanol; 1,1,2-Trichloro-1,2,2-trifluoroethane for 1h; Ambient temperature;70.9%
silver cyanate
3315-16-0

silver cyanate

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

C11H4F13N3O3Si

C11H4F13N3O3Si

Conditions
ConditionsYield
In benzene Heating;58%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl magnesium iodide
76598-01-1

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl magnesium iodide

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

tris(tridecafluoro-octyl)chlorosilane

tris(tridecafluoro-octyl)chlorosilane

Conditions
ConditionsYield
In diethyl ether for 18h; Heating;27%
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

1-bromo-4-(trifluorovinyloxy)benzene
134151-77-2

1-bromo-4-(trifluorovinyloxy)benzene

chloro-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-bis-(4-trifluorovinyloxy-phenyl)-silane

chloro-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-bis-(4-trifluorovinyloxy-phenyl)-silane

Conditions
ConditionsYield
Stage #1: 1-bromo-4-(trifluorovinyloxy)benzene With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 1h;
Stage #2: (tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane In diethyl ether; pentane at -78℃; for 24h;
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

3-[bis-(3-hydroxy-propyl)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-silanyl]-propan-1-ol

3-[bis-(3-hydroxy-propyl)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-silanyl]-propan-1-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: Mg / diethyl ether / 2 h / 0 - 5 °C
1.2: 82 percent / diethyl ether / 24 h / Heating
2.1: BH3 / tetrahydrofuran / 3 h / 20 °C
2.2: 76 percent / aq. NaOH; H2O2 / tetrahydrofuran / 2 h / 20 °C
View Scheme
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

3-[bis-(2,3-dihydroxy-propyl)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-silanyl]-propane-1,2-diol

3-[bis-(2,3-dihydroxy-propyl)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-silanyl]-propane-1,2-diol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: Mg / diethyl ether / 2 h / 0 - 5 °C
1.2: 82 percent / diethyl ether / 24 h / Heating
2.1: 67 percent / NMNO*H2O; aq. osmium tetraoxide / acetone / 20 °C
View Scheme
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

tris(tridecafluoro-octyl)fluorosilane

tris(tridecafluoro-octyl)fluorosilane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 27 percent / diethyl ether / 18 h / Heating
2: 40percent HF / diethyl ether / Ambient temperature
View Scheme
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

tris(tridecafluoro-octyl)trifluoropropylsilane

tris(tridecafluoro-octyl)trifluoropropylsilane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 27 percent / diethyl ether / 18 h / Heating
2: 40percent HF / diethyl ether / Ambient temperature
3: 58 percent / diethyl ether / 1.) -33 deg C, 5 h, 2.) RT, 3 d
View Scheme
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

C26H43F13O12Si
887651-67-4

C26H43F13O12Si

Conditions
ConditionsYield
at 150℃; under 15.0015 - 37.5038 Torr; for 2.5h;
isopropyllithium
1888-75-1

isopropyllithium

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

C19H27F13Si2

C19H27F13Si2

Conditions
ConditionsYield
Stage #1: trimethylsilylacetylene With n-butyllithium In tetrahydrofuran; hexane for 1h; Cooling with ice bath;
Stage #2: (tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane In tetrahydrofuran; hexane for 5.75h;
Stage #3: isopropyllithium With ammonium chloride In tetrahydrofuran; hexane; water; pentane at 0 - 20℃;
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
78560-45-9

(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane

A

(tridecafluorooctyl)dichlorosilane

(tridecafluorooctyl)dichlorosilane

B

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With trihexyl(tetradecyl)phosphonium chloride; dimethylmonochlorosilane at 60 - 85℃; Inert atmosphere;
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