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| CAS No.: | 78560-45-9 | ||||||||||||||||||||
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| Name: | 1H,1H,2H,2H-PERFLUOROOCTYLTRICHLOROSILANE | ||||||||||||||||||||
| Molecular Structure: | |||||||||||||||||||||
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| Formula: | C8H4 Cl3 F13 Si | ||||||||||||||||||||
| Molecular Weight: | 481.543 | ||||||||||||||||||||
| Synonyms: | (1,1,2,2-Tetrahydroperfluorooctyl)trichlorosilane;(1H,1H,2H,2H-Tridecafluorooctyl)trichlorosilane;(Tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane;3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyltrichlorosilane;Dynasylan 8061;Perfluoro-1,1,2,2-tetrahydrooctyltrichlorosilane;Perfluorohexylethyltrichlorosilane;SIT 8174.0;T 2492;TSL 8256;Trichloro(tridecafluoro-1,1,2,2-tetrahydrooctyl)silane;Tridecafluoro-1,1,2,2-tetrahydroctyl-1-trichlorosilane;[2-(Perfluorohexyl)ethyl]trichlorosilane; | ||||||||||||||||||||
| EINECS: | 278-947-6 | ||||||||||||||||||||
| Density: | 1.3 g/mL at 25 °C(lit.) | ||||||||||||||||||||
| Melting Point: | -32°C | ||||||||||||||||||||
| Boiling Point: | 192 °C(lit.) | ||||||||||||||||||||
| Flash Point: | 189 °F | ||||||||||||||||||||
| Solubility: | 580μg/L at 20℃ | ||||||||||||||||||||
| Appearance: | colourless liquid | ||||||||||||||||||||
| Hazard Symbols: |
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| Risk Codes: | 14-34 | ||||||||||||||||||||
| Safety: |
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| PSA: | 0.00000 | ||||||||||||||||||||
| LogP: | 6.77060 | ||||||||||||||||||||
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3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene
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(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
| Conditions | Yield |
|---|---|
| With trichlorosilane In 5,5-dimethyl-1,3-cyclohexadiene | 99% |
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3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene
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(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
| Conditions | Yield |
|---|---|
| With dihydrogen hexachloroplatinate; trichlorosilane at 100℃; for 70h; | 98% |
| With dihydrogen hexachloroplatinate; trichlorosilane In isopropyl alcohol at 100℃; | 83% |
| With trichlorosilane; chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex at 60℃; for 4h; | 80% |
| With dihydrogen hexachloroplatinate; trichlorosilane In isopropyl alcohol at 100℃; for 18h; | 79% |
| With trichlorosilane; platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane In xylene at 86 - 126℃; under 760.051 - 5625.56 Torr; for 4.5 - 10.5h; Product distribution / selectivity; | 2.6% |
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3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene
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trichlorosilane
- 78560-45-9
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
| Conditions | Yield |
|---|---|
| platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In xylene at 110℃; under 18751.9 Torr; for 192h; Industry scale; |
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(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
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(1H,1H,2H,2H-tridecafluoro-octyl)trifluorosilane
| Conditions | Yield |
|---|---|
| With hydrogen fluoride In ethanol at 0℃; | 99% |
| With hydrogen fluoride In diethyl ether; ethanol Ambient temperature; Yield given; |
- 307531-92-6
1,3,5,7,9,11,14-heptaisobutyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol
- 78560-45-9
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
| Conditions | Yield |
|---|---|
| With triethylamine In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; | 98% |
- 78560-45-9
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
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1,3,5,7,9,11,14-heptacyclopentyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol
| Conditions | Yield |
|---|---|
| With triethylamine In tetrahydrofuran at 20℃; for 0.416667h; Inert atmosphere; | 92% |
| Conditions | Yield |
|---|---|
| at 0℃; for 7h; Inert atmosphere; Neat (no solvent); | 90% |
- 106-95-6
allyl bromide
- 78560-45-9
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
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1H,1H,2H,2H-perfluorooctyltriallylsilane
| Conditions | Yield |
|---|---|
| Stage #1: allyl bromide With magnesium In diethyl ether at 0 - 5℃; for 2h; Stage #2: (tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane In diethyl ether for 24h; Heating; | 82% |
- 78560-45-9
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
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tridecafluoro-1,1,2,2-tetrahydrooctylhepta(3,3,3-trifluoropropyl)-T8-silsesquioxane
| Conditions | Yield |
|---|---|
| With triethylamine In tetrahydrofuran at 20℃; for 3h; | 82% |
| With triethylamine In tetrahydrofuran Inert atmosphere; |
- 124-41-4
sodium methylate
- 78560-45-9
(tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane
| Conditions | Yield |
|---|---|
| In methanol; 1,1,2-Trichloro-1,2,2-trifluoroethane for 1h; Ambient temperature; | 70.9% |
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Specification
1H,1H,2H,2H-perfluorooctyl trichlorosilane, with the CAS Number 78560-45-9, has the Synonyms of 1H,1H,2H,2H-Perfluorooctyltrichlorosilane; Trichloro-1H,1H,2H,2H-perfluorooctylsilane; (Tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane; Perfluorooctyltrichlorosilane; Trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane. It is Colorless to pink liquid and should be stored at room temperature. It has the Molecular Formula of C8H4Cl3F13Si and the Molecular Weight of 481.5411.
Physical properties about 1H,1H,2H,2H-perfluorooctyl trichlorosilane are: (1)ACD/LogP: 6.036; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.04; (4)ACD/LogD (pH 7.4): 6.04; (5)ACD/BCF (pH 5.5): 22776.01; (6)ACD/BCF (pH 7.4): 22776.01; (7)ACD/KOC (pH 5.5): 45779.22; (8)ACD/KOC (pH 7.4): 45779.22; (9)#Freely Rotating Bonds: 7; (10)Index of Refraction: 1.346; (11)Molar Refractivity: 64.3 cm3; (12)Molar Volume: 301.59 cm3; (13)Polarizability: 25.49 10-24cm3; (14)Surface Tension: 17.753999710083 dyne/cm; (15)Density: 1.597 g/cm3; (16)Flash Point: 74.332 °C; (17)Enthalpy of Vaporization: 41.77 kJ/mol; (18)Boiling Point: 199.296 °C at 760 mmHg; (19)Vapour Pressure: 0.486000001430511 mmHg at 25°C
When you are using this chemical, please be cautious about it as the following:
1. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
2. Take off immediately all contaminated clothing;
3. Wear suitable protective clothing, gloves and eye/face protection;
4. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible);
You can still convert the following datas into molecular structure:
(1)InChI=1S/C8H4Cl3F13Si/c9-25(10,11)2-1-3(12,13)4(14,15)5(16,17)6(18,19)7(20,21)8(22,23)24/h1-2H2;
(2)InChIKey=PISDRBMXQBSCIP-UHFFFAOYSA-N;
(3)SmilesC(C(C(C(CC[Si](Cl)(Cl)Cl)(F)F)(F)F)(F)F)(C(C(F)(F)F)(F)F)(F)F