78602-05-8

Upstream product

• 3558-24-5 1-methyl-2-phenyl-1H-indole 
• 94-36-0 dibenzoyl peroxide 
• 1757-72-8 1-methyl-2-phenyl-1H-indole-3-carbaldehyde 
• 62367-64-0 1-(1-methyl-2-phenyl-1H-indol-3-yl)ethan-1-one 
• 78395-78-5 1-methyl-2-phenyl-3-hydroxymethylindole 
• 4677-05-8 3-(phenyldiazenyl)-1-methyl-2-phenyl-1H-indole 
• 78602-02-5 3-(1H-Indol-3-ylmethyl)-1-methyl-2-phenyl-1H-indole 
• 5344-90-1 2-Aminobenzyl alcohol 
• 6289-87-8 N-(2-(hydroxymethyl)phenyl)benzamide 
• 33768-43-3 N-(2-formylphenyl)benzamide 
• 62295-27-6 N-(2-formylphenyl)-N-methylbenzamide 
• 98-88-4 benzoyl chloride 

Downstream Products

• 82665-92-7 3-chloro-1-methyl-2-phenyl-1H-indole 
• 82665-93-8 5-Chloro-1,1'-dimethyl-2,2'-diphenyl-1,2-dihydro-1'H-[2,3']biindolyl-3-one 
• 82665-94-9 5,7-Dichloro-1,1'-dimethyl-2,2'-diphenyl-1,2-dihydro-1'H-[2,3']biindolyl-3-one 
• 138528-59-3 7-Chloro-1,1'-dimethyl-2,2'-diphenyl-1,2-dihydro-1'H-[2,3']biindolyl-3-one 
• 58863-88-0 1,1'-dimethyl-2,2'-diphenyl-1,2-dihydro-1'H-[2,3']bisindolyl-3-one 

Relevant academic research and scientific papers

Preparation of functional benzofurans, benzothiophenes, and indoles using ester, thioester, and amide via intramolecular wittig reactions

Preparation of new types of highly functional benzofurans, benzothiophenes, and indoles is realized via intramolecular Wittig reactions with the corresponding ester, thioester, and amide functionalities. The key intermediates, phosphorus ylides, presumably result from the addition of Bu 3P toward aldehydes followed by acylation and deprotonation. Synthesis of functional benzofurans directly starting from salicylic aldehyde derivatives with acid chlorides in a one-step procedure is also developed.

IPSO-SUBSTITUTIONS. REACTIONS OF 3-SUBSTITUTED INDOLES WITH BENZOYLPEROXIDE

3-substituted indoles with benzoylperoxide led to the 3-benzoyloxy derivative.The reaction is discussed in terms of homolytic ipso-substitution.