78684-69-2

Basic information

• Product Name: TRANS-2-BROMO-1-INDANOL)
• CAS NO: 78684-69-2
• Molecular Weight: 0
• Mol File: 78684-69-2.mol
• Article Data: 56

Chemical Properties

• Appearance: /
• CAS DataBase Reference: TRANS-2-BROMO-1-INDANOL)(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-2-BROMO-1-INDANOL)(78684-69-2)
• EPA Substance Registry System: TRANS-2-BROMO-1-INDANOL)(78684-69-2)

Safety Data

• Hazardous Substances Data: 78684-69-2(Hazardous Substances Data)

Upstream product

• 506-68-3 bromocyane 
• 95-13-6 1-indene 
• 7732-18-5 water 
• 79-15-2 N-bromoacetamide 
• 20357-79-3 1,2-dibromoindane 
• 67-64-1 acetone 
• 50870-60-5 2-bromo-2-indene-1-one 
• 1775-27-5 2-bromoindanone 
• 10368-44-2 trans-2-bromo-1-indanol 
• 24373-98-6 1-bromoindane 
• 108-22-5 Isopropenyl acetate 
• 615-13-4 2-indanone 
• 4254-31-3 2-acetoxyindane 
• 4254-29-9 indan-2-ol 

Downstream Products

• 67528-24-9 (1S,2S)-2-bromo-2,3-dihydro-1H-inden-1-ol 
• 79465-06-8 trans-2-bromo-1-indanol 
• 85354-34-3 (1R,2R)-(-)-2-bromo-1-acetoxyindan 
• 1775-27-5 2-bromoindanone 
• 180681-90-7 (1S,2R)-2-bromo-2,3-dihydro-1H-inden-1-ol 
• 768-22-9 (1aR,6aS)-6,6a-dihydro-1aH-indeno[1,2-b]oxirene 
• 142678-92-0 (1R,2S)-amino indanol 
• 100914-98-5 2-(phenylsulfonyl)-2,3-dihydro-1H-inden-1-one 
• 108475-91-8 (+/-)-cis-2-benzenesulfonyl-indan-1-ol 
• 108475-91-8 (+/-)-trans-2-benzenesulfonyl-indan-1-ol 
• 32785-03-8 (1RS)-trans-2-((SR)-benzenesulfinyl)-indan-1-ol 

Relevant articles and documents

The absolute configuration of 2-bromo-2,3-dihydro-1H-inden-1-ols

All four possible stereoisomers of cis- and trans-2-bromo-2,3-dihydro-1H-inden-1-ols, which are important intermediates in the synthesis of biologically active compounds, were synthesized and their configurations were studied by enzymatic kinetic resoluti

Electrochemical bromofunctionalization of alkenes in a flow reactor

The bromination of organic molecules has been extensively studied to date, yet there is still a demand for safe and sustainable methodologies. Hazardous reagents, selectivity, low atom economy and waste production are the most persisting problems of brominating reagents. The electrochemical oxidation of bromide to bromine is a viable strategy to reduce waste by avoiding chemical oxidants. Furthermore, thein situgeneration of reactive intermediates minimizes the risk of hazardous reagents. In this work, we investigate the electrochemical generation of bromine from hydrobromic acid in a flow electrochemical reactor. Various alkenes could be converted to their corresponding dibromides, bromohydrines, bromohydrin ethers and cyclized products in good to excellent yields.

Concurrent Formation of N-H Imines and Carbonyl Compounds by Ruthenium-Catalyzed C-C Bond Cleavage of β-Hydroxy Azides

A commercial cyclopentadienylrutenium dicarbonyl dimer ([CpRu(CO)2]2) efficiently catalyzes the formation of N-H imines and carbonyl compounds simultaneously from β-hydroxy azides via C-C bond cleavage under visible light. Density functional theory calculations for the cleavage reaction support the mechanism involving chelation of alkoxy azide species and liberation of nitrogen as the driving force. The synthetic utility of the reaction was demonstrated by a new amine synthesis promoted by chemoselective allylation of imine and synthesis of isoquinoline.