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  • 2031-67-6 Structure
  • Basic information

    1. Product Name: Methyltriethoxysilane
    2. Synonyms: Monomethyltriethoxysilane;Silquest A;Methyltriethoxysilane, 98+% 250ML;Methyltriethoxysilane, 98+% 25ML;HD-120;Triethoxymethylsilane technical grade, 90%;Methyltriethoxysilane, Triethoxy methyl silane;MTES
    3. CAS NO:2031-67-6
    4. Molecular Formula: C7H18O3Si
    5. Molecular Weight: 178.3
    6. EINECS: 217-983-9
    7. Product Categories: organosilicon compounds;silane;Silicone series;Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Silane Coupling Agents (Intermediates);Si-O Compounds;Trialkoxysilanes;Alkoxy Silanes;Crosslinkers;Crosslinking Agents;Silane series
    8. Mol File: 2031-67-6.mol
    9. Article Data: 31
  • Chemical Properties

    1. Melting Point: <-40°C
    2. Boiling Point: 141-143 °C(lit.)
    3. Flash Point: 75 °F
    4. Appearance: colorless/liquid
    5. Density: 0.895 g/mL at 25 °C(lit.)
    6. Vapor Density: >1 (vs air)
    7. Vapor Pressure: 11 mm Hg ( 20 °C)
    8. Refractive Index: n20/D 1.383(lit.)
    9. Storage Temp.: Flammables area
    10. Solubility: N/A
    11. Water Solubility: INSOLUBLE
    12. Sensitive: Moisture Sensitive
    13. Stability: Stability Moisture-sensitive. Flammable - note low flash point. Incompatible with acids, oxidizing agents, moisture, water.
    14. BRN: 1742453
    15. CAS DataBase Reference: Methyltriethoxysilane(CAS DataBase Reference)
    16. NIST Chemistry Reference: Methyltriethoxysilane(2031-67-6)
    17. EPA Substance Registry System: Methyltriethoxysilane(2031-67-6)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: 10
    3. Safety Statements: 16
    4. RIDADR: UN 1993 3/PG 3
    5. WGK Germany: 3
    6. RTECS: VV4640000
    7. F: 10-21
    8. TSCA: Yes
    9. HazardClass: 3
    10. PackingGroup: III
    11. Hazardous Substances Data: 2031-67-6(Hazardous Substances Data)

2031-67-6 Usage

Description

Methyltriethoxysilane, an alkylalkoxysilane, is a clear, colorless liquid with an odor characteristic of alcohols. It hydrolyzes slowly in the presence of moisture to form reactive silanols, which further react to produce oligosiloxanes and then polysiloxanes. It is a versatile compound with various applications across different industries.

Uses

Used in Chemical Industry:
Methyltriethoxysilane is used as a crosslinking agent and an adhesion promoter for the production of silicone polymers or silicone resin. Its high reactivity, facilitated by nucleophilic substitution in the presence of acid or base catalysts, makes it an important component in sol-gel systems.
Used in Surface Treatment:
In the surface treatment industry, Methyltriethoxysilane is used as a filler modifier to render a wide range of surfaces and materials water repellent, such as mineral fillers, pigments, glass, and cardboard. It can be used pure or in solution, and may require pre-treatment of the substrate with water and/or a catalyst.
Used in Non-Metal Surface Treatment:
Methyltriethoxysilane is utilized in the non-metal surface treatment industry to enhance the properties of various materials, providing water repellency and improved adhesion.
Used in Polymer Preparation:
Methyltriethoxysilane is employed in the preparation of non-aqueous polymers, contributing to the development of materials with specific characteristics and applications.
Used in Semiconductor Manufacturing:
Methyltriethoxysilane finds application in the manufacture of semiconductors, where its properties are crucial for the production process and the performance of the final product.
Used in Coatings and Sealants:
It is also used in the formulation of coatings and sealants, where its ability to promote adhesion and act as a crosslinking agent enhances the performance and durability of these products.

Flammability and Explosibility

Flammable

Check Digit Verification of cas no

The CAS Registry Mumber 2031-67-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,0,3 and 1 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 2031-67:
(6*2)+(5*0)+(4*3)+(3*1)+(2*6)+(1*7)=46
46 % 10 = 6
So 2031-67-6 is a valid CAS Registry Number.
InChI:InChI=1/C7H18O3Si/c1-5-8-11(4,9-6-2)10-7-3/h5-7H2,1-4H3

2031-67-6 Well-known Company Product Price

  • Brand
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  • Alfa Aesar

  • (L04059)  Methyltriethoxysilane, 98%   

  • 2031-67-6

  • 250ml

  • 404.0CNY

  • Detail
  • Alfa Aesar

  • (L04059)  Methyltriethoxysilane, 98%   

  • 2031-67-6

  • 1000ml

  • 1402.0CNY

  • Detail
  • Aldrich

  • (175579)  Triethoxymethylsilane  99%

  • 2031-67-6

  • 175579-50G

  • 472.68CNY

  • Detail
  • Aldrich

  • (175579)  Triethoxymethylsilane  99%

  • 2031-67-6

  • 175579-250G

  • 785.07CNY

  • Detail
  • Aldrich

  • (339644)  Triethoxymethylsilane  technical grade, 90%

  • 2031-67-6

  • 339644-500ML

  • 548.73CNY

  • Detail

2031-67-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Methyltriethoxysilane

1.2 Other means of identification

Product number -
Other names CM9050

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2031-67-6 SDS

2031-67-6Synthetic route

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

sodium ethanolate
141-52-6

sodium ethanolate

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
In ethanol for 3h;99%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

ethanol
64-17-5

ethanol

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With polyaniline at 50 - 55℃; for 5h;98.3%
diethoxymethylane
2031-62-1

diethoxymethylane

A

methylsilane
992-94-9

methylsilane

B

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
dimethyltitanocene at 50℃; for 0.5h;A 87%
B 96%
dimethyltitanocene at 50℃; for 0.5h; various silanes, other amount if dimethyltitanocene, with solvent, other time and temp.;A 87%
B 96%
With sodium t-butanolate In toluene at 20℃; Inert atmosphere;
With sodium t-butanolate In tetrahydrofuran-d8 at 20℃; for 0.166667h; Sealed tube; Inert atmosphere;
tris(ethylthio)methylsilane
71520-43-9

tris(ethylthio)methylsilane

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

A

tris(ethylsulfanyl)methane
6267-24-9

tris(ethylsulfanyl)methane

B

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With zinc(II) chloride In toluene at 0℃; for 5h;A 90%
B 88%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

A

ethoxy(methyl)dichlorosilane
1825-75-8

ethoxy(methyl)dichlorosilane

B

chloro(diethoxy)(methyl)silane
18157-20-5

chloro(diethoxy)(methyl)silane

C

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
at 20 - 22℃; for 150h;A 12%
B 80%
C 6.5%
penta-Si-ethoxy-Si-methyl-Si,Si'-methanediyl-bis-silane
18055-95-3

penta-Si-ethoxy-Si-methyl-Si,Si'-methanediyl-bis-silane

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With potassium hydroxide In ethanol Heating;70%
diethoxymethylane
2031-62-1

diethoxymethylane

methylvinyldiethoxysilane
5507-44-8

methylvinyldiethoxysilane

A

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

B

1,2-bis(diethoxymethylsilyl)ethane
18043-74-8

1,2-bis(diethoxymethylsilyl)ethane

Conditions
ConditionsYield
[RuCl(NCCH3)5][RuCl4(NCCH3)2] at 100℃; for 2h;A 12 % Chromat.
B 55%
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

[MnMe(μ-Me)(1,3-bis(2,4,6-trimethylphenyl)imidazole-2-ylidene)]2

[MnMe(μ-Me)(1,3-bis(2,4,6-trimethylphenyl)imidazole-2-ylidene)]2

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
In benzene at 100℃; for 30h; Inert atmosphere;47%
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

[MnMe(μ-Me)(1,3-diisopropyl-4,5-dimethylimidazole-2-ylidene)]2

[MnMe(μ-Me)(1,3-diisopropyl-4,5-dimethylimidazole-2-ylidene)]2

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
In benzene at 80℃; for 60h; Inert atmosphere; Schlenk technique;43%
tris(ethylthio)methylsilane
71520-43-9

tris(ethylthio)methylsilane

2-Ethoxy-5,5-dimethyl-1,3-dioxane
5783-79-9

2-Ethoxy-5,5-dimethyl-1,3-dioxane

A

tris(ethylsulfanyl)methane
6267-24-9

tris(ethylsulfanyl)methane

B

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

C

2-ethoxy-2,5,5-trimethyl-1,2-dioxa-2-silacyclohexane

2-ethoxy-2,5,5-trimethyl-1,2-dioxa-2-silacyclohexane

Conditions
ConditionsYield
With hydrogenchloride In toluene at 40℃; for 8h;A 41%
B 20%
C 40%
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

[MnMe(μ-Me)(1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene)]2

[MnMe(μ-Me)(1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene)]2

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
In benzene at 100℃; for 12h; Inert atmosphere;21%
Dichloromethylsilane
75-54-7

Dichloromethylsilane

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With AlCl3 CH3SiHCl2 and HC(OC2H5)3 in presence of AlCl3;;16%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

ethanol
64-17-5

ethanol

A

chloro(diethoxy)(methyl)silane
18157-20-5

chloro(diethoxy)(methyl)silane

B

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
at 0 - 20℃;A n/a
B 0.33%
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

methylene chloride
74-87-3

methylene chloride

A

diethoxy dimethylsilane
78-62-6

diethoxy dimethylsilane

B

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With magnesium
With magnesium
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

methylene chloride
74-87-3

methylene chloride

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With amalgamated copper; sodium
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
auf 120grad,160grad,200grad,250grad,290grad,295grad und 300grad erhitzt, indem jedesmal nach mehrstuendigem Erhitzen dei gebildeten Gase abgelassen werden;
With Na In neat (no solvent) Si(OC2H5)4 and Zn(CH3)2 with Na at 300°C;;
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

methylmagnesium bromide
75-16-1

methylmagnesium bromide

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

A

ethoxy(methyl)dichlorosilane
1825-75-8

ethoxy(methyl)dichlorosilane

B

trichloroethoxysilane
1825-82-7

trichloroethoxysilane

C

chloro(diethoxy)(methyl)silane
18157-20-5

chloro(diethoxy)(methyl)silane

D

dichlorodiethoxysilane
4667-38-3

dichlorodiethoxysilane

E

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

F

chlorotriethoxysilane
4667-99-6

chlorotriethoxysilane

Conditions
ConditionsYield
N,N-dimethyl-formamide at 90℃; for 5.5h; Product distribution; Thermodynamic data; Equilibrium constant; ΔG0, ΔH0;
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

ethanol
64-17-5

ethanol

A

ethoxy(methyl)dichlorosilane
1825-75-8

ethoxy(methyl)dichlorosilane

B

chloro(diethoxy)(methyl)silane
18157-20-5

chloro(diethoxy)(methyl)silane

C

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
at 19.9℃; Product distribution; Rate constant;
at 24.9℃; Thermodynamic data; Equilibrium constant; ΔH0, ΔS0, ΔG0;
chloromethyltriethoxysilane
15267-95-5

chloromethyltriethoxysilane

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With ethanol; magnesium 1.) THF, 0 to 20 deg C; Yield given. Multistep reaction;
ethyl bromide
74-96-4

ethyl bromide

tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

chlorobenzene
108-90-7

chlorobenzene

A

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

B

diethoxy-methyl-phenyl-silane
775-56-4

diethoxy-methyl-phenyl-silane

Conditions
ConditionsYield
With methyl bottoms Product distribution; various compositions of methyl bottoms, various supply rates;
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

methylene chloride
74-87-3

methylene chloride

magnesium

magnesium

A

diethoxy dimethylsilane
78-62-6

diethoxy dimethylsilane

B

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

A

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

B

methyl zinc ethylate

methyl zinc ethylate

ethanol
64-17-5

ethanol

chloro(diethoxy)(methyl)silane
18157-20-5

chloro(diethoxy)(methyl)silane

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
at 20℃; Kinetics; Equilibrium constant;
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With methylene chloride In neat (no solvent) introduction of CH3Cl into Si(OC2H5)4 at 120°C in presence of Na and small amt. of Cu-amalgam;;
In not given Si(OC2H5)4 and methyl magnesium halides;;
With CH3MgI In not given Si(OC2H5)4 and CH3MgI at 150°C;;
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

A

ethyl trimethylsilyl ether
1825-62-3

ethyl trimethylsilyl ether

B

diethoxy dimethylsilane
78-62-6

diethoxy dimethylsilane

C

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With methylene chloride; magnesium In neat (no solvent)
With methylene chloride; magnesium In neat (no solvent)
With CH3Cl; Mg In neat (no solvent)
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

Conditions
ConditionsYield
With C2H5OH; C6H5N(CH3)2 or C5H5N
With ethanol
diethoxymethylane
2031-62-1

diethoxymethylane

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

A

chloropropyl(ethoxy)(methyl)silyl chloride
688004-16-2

chloropropyl(ethoxy)(methyl)silyl chloride

B

chloro(diethoxy)(methyl)silane
18157-20-5

chloro(diethoxy)(methyl)silane

C

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

D

1-diethoxymethylsilylpropane
70017-39-9

1-diethoxymethylsilylpropane

E

3-chloropropylmethyldiethoxysilane
13501-76-3

3-chloropropylmethyldiethoxysilane

Conditions
ConditionsYield
Stage #1: diethoxymethylane; ruthenium trichloride at 20 - 80℃; Under N2 atmosphere;
Stage #2: 3-chloroprop-1-ene at 80℃; for 1h; Under N2 atmosphere;
Brookhart's acid

Brookhart's acid

diethoxymethylane
2031-62-1

diethoxymethylane

A

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

B

1,1,3,3-tetraethoxy-1,3-dimethyldisiloxane
18001-60-0

1,1,3,3-tetraethoxy-1,3-dimethyldisiloxane

Conditions
ConditionsYield
With norborn-2-ene; 1-methylindole In toluene at 80℃; for 18h; Glovebox; Inert atmosphere;
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

sodium diethoxy(methyl)silanolate
127177-29-1

sodium diethoxy(methyl)silanolate

Conditions
ConditionsYield
With sodium hydroxide In ethanol at 10 - 25℃; for 1h; Concentration; Inert atmosphere;99%
With sodium hydroxide at 20℃; Inert atmosphere;98%
With sodium hydroxide at 0 - 25℃;96%
tetrabutoxytitanium

tetrabutoxytitanium

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

glycerol
56-81-5

glycerol

methyltris(2,3-dihydroxypropoxy)silane•tetrakis(2,3-dihydroxypropoxy)titanium•11(glycerol)

methyltris(2,3-dihydroxypropoxy)silane•tetrakis(2,3-dihydroxypropoxy)titanium•11(glycerol)

Conditions
ConditionsYield
at 60 - 140℃; for 15h;99%
tetrabutoxytitanium

tetrabutoxytitanium

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

glycerol
56-81-5

glycerol

2[methyltris(2,3-dihydroxypropoxy)silane]•tetrakis(2,3-dihydroxypropoxy)titanium•12(glycerol)

2[methyltris(2,3-dihydroxypropoxy)silane]•tetrakis(2,3-dihydroxypropoxy)titanium•12(glycerol)

Conditions
ConditionsYield
at 60 - 140℃; for 15h;99%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

triethylamine
121-44-8

triethylamine

tetraethylammonium fluorosulfonate
86759-27-5

tetraethylammonium fluorosulfonate

Conditions
ConditionsYield
With fluorosulfonyl fluoride In chlorobenzene at 20℃; for 12h; Solvent; Sealed tube;99%
With fluorosulfonyl fluoride In chlorobenzene at 23 - 27℃; for 12h;99%
dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

dodecamethyldodeca(dimethylhydro)cyclododecasilsesquioxane

dodecamethyldodeca(dimethylhydro)cyclododecasilsesquioxane

Conditions
ConditionsYield
Stage #1: dimethylmonochlorosilane; Methyltriethoxysilan With copper dichloride Alkaline conditions;
Stage #2: dimethylmonochlorosilane With pyridine In toluene at 25℃; for 24h;
98%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

ethoxy(methyl)dichlorosilane
1825-75-8

ethoxy(methyl)dichlorosilane

Conditions
ConditionsYield
at 200℃; for 6h; Temperature; Molecular sieve; Large scale;98%
With bismuth(III) chloride at 25℃; for 24h; Inert atmosphere;85%
With bismuth(III) chloride at 20℃; for 24h; Schlenk technique; Inert atmosphere;50 mol
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

N-(3,5-dimethoxybenzyl)-N-ethylethanamine
90704-70-4

N-(3,5-dimethoxybenzyl)-N-ethylethanamine

N-(3,5-dimethoxybenzyl)-N,N-diethylethanaminium sulfofluoridate

N-(3,5-dimethoxybenzyl)-N,N-diethylethanaminium sulfofluoridate

Conditions
ConditionsYield
With fluorosulfonyl fluoride In chlorobenzene at 20℃; for 12h; Solvent; Sealed tube;97%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Potassium; 2-(2-methyl-benzo[1,3,2]dioxasilol-2-yloxy)-phenolate

Potassium; 2-(2-methyl-benzo[1,3,2]dioxasilol-2-yloxy)-phenolate

Conditions
ConditionsYield
With potassium ethoxide In ethanol Heating;96%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

1,1,3,3-tetraethoxy-1,3-dimethyldisiloxane
18001-60-0

1,1,3,3-tetraethoxy-1,3-dimethyldisiloxane

Conditions
ConditionsYield
With hydrogenchloride; water In ethanol for 5h; Reagent/catalyst; Cooling with ice; Large scale;92.7%
In not given partial hydrolysis;;
perfluorooctyl sulfofluorure
307-35-7

perfluorooctyl sulfofluorure

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

triethylamine
121-44-8

triethylamine

perfluorooctanesulfonic acid, tetraethylammonium salt

perfluorooctanesulfonic acid, tetraethylammonium salt

Conditions
ConditionsYield
In further solvent(s) 20°C, slight warming, 8 h, solvent: C6H5Cl;92%
In further solvent(s) 20°C, slight warming, 8 h, solvent: C6H5Cl;92%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

octamethylsilsesquioxane
17865-85-9

octamethylsilsesquioxane

Conditions
ConditionsYield
With hydrogenchloride; water; triethylamine In formic acid; acetone; acetonitrile at 20℃; for 48h; Reflux;88%
With water; potassium hydroxide In methanol at 60℃; for 72h;83.6%
With potassium hydroxide In methanol; water at 60℃; for 72h;83.6%
Stage #1: Methyltriethoxysilan With 2-methyl-2-propenoic acid 2-hydroxyethyl ester at 50 - 95℃; for 52h; bulk polymerization;
Stage #2: With ammonium hydroxide In methanol at 40℃; for 72h;
22.94%
With potassium hydroxide und Erhitzen des Reaktionsprodukts auf 300grad;
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

1,2-dihydroxy-4-nitrobenzene
3316-09-4

1,2-dihydroxy-4-nitrobenzene

Potassium; 2-(2-methyl-5-nitro-benzo[1,3,2]dioxasilol-2-yloxy)-5-nitro-phenolate

Potassium; 2-(2-methyl-5-nitro-benzo[1,3,2]dioxasilol-2-yloxy)-5-nitro-phenolate

Conditions
ConditionsYield
With potassium ethoxide In ethanol Heating;88%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

1-aza-4,6,11-trioxa-5-boratricyclo[3.3.3.0(1,5)]undecane
15277-97-1

1-aza-4,6,11-trioxa-5-boratricyclo[3.3.3.0(1,5)]undecane

A

triethyl borate
150-46-9

triethyl borate

B

1-methylsilatrane
23908-48-7

1-methylsilatrane

Conditions
ConditionsYield
With aluminum (III) chloride In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux;A n/a
B 86%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

water
7732-18-5

water

silicon oxycarbide

silicon oxycarbide

Conditions
ConditionsYield
With hydrogenchloride In ethanol alkoxide dissolved, hydrolyzed with water (pH=1 by HCl) at 70 °C,maintained at 70 °C for 20 min, pirolyzed at 1000 °C for 1 h in Ar; elem. anal., powder XRD;85.9%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

water
7732-18-5

water

silicon oxycarbide

silicon oxycarbide

Conditions
ConditionsYield
With hydrogenchloride In ethanol alkoxide dissolved, hydrolyzed with water (pH=1 by HCl) at 70 °C,maintained at 70 °C for 20 min, pyrolyzed at 1200 °C for 1 h in Ar; elem. anal., power XRD;85.9%
With HCl; ammonia In ethanol; water addn. of aq. HCl at pH 4.9 to a refluxing silicon compd. in ethanol, stirring for 20 min, cooling to room temp., addn. of ammonia soln., stirring for 2-3 min, pyrolysis under Ar by heating to 1200°C at 5°C /min, standing for 1 h; elem. anal., X-ray diffraction;
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

2,2-dimethyl-6-<2-(trimethylsiloxy)ethyl>-1,3,6,2-dioxazasilocane
135718-12-6

2,2-dimethyl-6-<2-(trimethylsiloxy)ethyl>-1,3,6,2-dioxazasilocane

1-methylsilatrane
2288-13-3

1-methylsilatrane

Conditions
ConditionsYield
With sodium isopropylate In isopropyl alcohol for 20h;85%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

1,1',1''-tris<(trimethylsiloxy)carbonyl>trimethylamine
51407-32-0

1,1',1''-tris<(trimethylsiloxy)carbonyl>trimethylamine

1-methylsilatrane-3,7,10-trione

1-methylsilatrane-3,7,10-trione

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 3h; Ambient temperature;85%
CF2Cl(CF2)5OCF2CF2SO2F
73606-14-1

CF2Cl(CF2)5OCF2CF2SO2F

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

triethylamine
121-44-8

triethylamine

C8ClF16O4S(1-)*C8H20N(1+)

C8ClF16O4S(1-)*C8H20N(1+)

Conditions
ConditionsYield
In chlorobenzene at 20℃; for 9h;85%
In chlorobenzene at 20℃;85%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

1,1',1''-tris<(trimethylsiloxy)carbonyl>trimethylamine
51407-32-0

1,1',1''-tris<(trimethylsiloxy)carbonyl>trimethylamine

1-Methyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane-3,7,10-trione; compound with N,N-dimethyl-formamide

1-Methyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane-3,7,10-trione; compound with N,N-dimethyl-formamide

Conditions
ConditionsYield
for 0.5h;83%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

methyl-tri-n-butylsilane
995-43-7

methyl-tri-n-butylsilane

Conditions
ConditionsYield
With n-C4H9Li In diethyl ether83%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

N,N-bis(2-hydroxyethyl)-L-serine

N,N-bis(2-hydroxyethyl)-L-serine

(4S)-(-)-1-methylsilatrane-4-carboxylic acid

(4S)-(-)-1-methylsilatrane-4-carboxylic acid

Conditions
ConditionsYield
With pyridine at 70 - 80℃; for 8h;82%
1-cyclohexylpiperidine
3319-01-5

1-cyclohexylpiperidine

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

1-cyclohexyl-1-ethylpiperidin-1-ium sulfofluoridate

1-cyclohexyl-1-ethylpiperidin-1-ium sulfofluoridate

Conditions
ConditionsYield
With fluorosulfonyl fluoride In chlorobenzene at 20℃; for 12h; Solvent; Sealed tube;82%
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

(1-adamantyl)dimethylamine
3717-40-6

(1-adamantyl)dimethylamine

(3s,5s,7s)-N-ethyl-N,N-dimethyladamantan-1-aminium sulfofluoridate

(3s,5s,7s)-N-ethyl-N,N-dimethyladamantan-1-aminium sulfofluoridate

Conditions
ConditionsYield
With fluorosulfonyl fluoride In chlorobenzene at 20℃; for 12h; Solvent; Sealed tube;82%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

A

ethoxy(methyl)dichlorosilane
1825-75-8

ethoxy(methyl)dichlorosilane

B

chloro(diethoxy)(methyl)silane
18157-20-5

chloro(diethoxy)(methyl)silane

Conditions
ConditionsYield
CH3SiCl3 and CH3Si(OC2H5)3 (1:2 mol) at 180°C;;A 8%
B 80.7%
In toluene Product distribution; equilibrium composition;A 75.8%
B 17.7%
CH3SiCl3 and CH3Si(OC2H5)3 (1:1 mol) at 180°C;;A 41.1%
B 32%
at 180℃;
Methyltriethoxysilan
2031-67-6

Methyltriethoxysilan

2-Methyl-6-(2-trimethylsilanyloxy-ethyl)-2-vinyl-[1,3,6,2]dioxazasilocane
144967-53-3

2-Methyl-6-(2-trimethylsilanyloxy-ethyl)-2-vinyl-[1,3,6,2]dioxazasilocane

1-methylsilatrane
2288-13-3

1-methylsilatrane

Conditions
ConditionsYield
With sodium isopropylate In isopropyl alcohol for 20h;80%

2031-67-6Related news

Mesoporous silica obtained with Methyltriethoxysilane (cas 2031-67-6) as co-precursor in alkaline medium07/14/2019

Mesoporous silica particles have been synthesized by sol–gel method from tetraethoxysilane (tetraethylorthosilicate, TEOS) and methyltriethoxysilane (MTES), in ethanol and water mixture, at different ratios of the of the silica precursors. Ammonia was used as catalyst at room temperature and he...detailed

Kinetic effects of methane on binary mixture separation on Methyltriethoxysilane (cas 2031-67-6) templated silica membranes07/12/2019

Separation characteristics and dynamic behavior of two binary mixtures, CO2/CH4 (50:50, vol%) and CH4/N2 (50:50, vol%), on methyltriethoxysilane templated silica (MTES) membrane were studied experimentally and theoretically. The permeation of the binary mixtures was compared with that of pure CO...detailed

A facile preparation of transparent Methyltriethoxysilane (cas 2031-67-6) based silica xerogel monoliths at ambient pressure drying07/11/2019

The highly transparent and hydrophobic methyltriethoxysilane (MTES) based silica xerogel monoliths with excellent integrity and low thermal conductivity were facilely synthesized by a novel method without complex steps of surface modification and solvent exchange via ambient pressure drying. The...detailed

2031-67-6Relevant articles and documents

-

Post, H. W.,Hofrichter, C. H.

, p. 572 - 577 (1940)

-

-

McBee et al.

, p. 1292 (1955)

-

TWO-COMPONENT SYSTEM FOR SMOOTHING AND CARE OF HAIR

-

, (2022/01/23)

-

Sustainable Catalytic Synthesis of Diethyl Carbonate

Putro, Wahyu S.,Ikeda, Akira,Shigeyasu, Shinji,Hamura, Satoshi,Matsumoto, Seiji,Lee, Vladimir Ya.,Choi, Jun-Chul,Fukaya, Norihisa

, p. 842 - 846 (2020/12/07)

New sustainable approaches should be developed to overcome equilibrium limitation of dialkyl carbonate synthesis from CO2 and alcohols. Using tetraethyl orthosilicate (TEOS) and CO2 with Zr catalysts, we report the first example of sustainable catalytic synthesis of diethyl carbonate (DEC). The disiloxane byproduct can be reverted to TEOS. Under the same conditions, DEC can be synthesized using a wide range of alkoxysilane substrates by investigating the effects of the number of ethoxy substituent in alkoxysilane substrates, alkyl chain, and unsaturated moiety on the fundamental property of this reaction. Mechanistic insights obtained by kinetic studies, labeling experiments, and spectroscopic investigations reveal that DEC is generated via nucleophilic ethoxylation of a CO2-inserted Zr catalyst and catalyst regeneration by TEOS. The unprecedented transformation offers a new approach toward a cleaner route for DEC synthesis using recyclable alkoxysilane.

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