79754-50-0

Upstream product

• 67295-38-9 1, 2-bis(4-methoxyphenyl)prop-2-en-1-one 
• 105-53-3 diethyl malonate 
• 101018-40-0 1,1-bis(4-methoxyphenyl)prop-2-en-1-ol 
• 685-87-0 Diethyl 2-bromomalonate 
• 123-11-5 4-methoxy-benzaldehyde 
• 728-87-0 4,4'-Dimethoxybenzhydrol 

Downstream Products

• 79754-48-6 4,5-bis-(p-methoxyphenyl)pentanoic acid 
• 79754-57-7 7-methoxy-4-p-methoxybenzyl-1,2,3,4-tetrahydro-1-naphthol 
• 79754-56-6 7-methoxy-4-p-methoxybenzyl-3,4-dihydronaphthalen-1(2H)-one 
• 79754-54-4 7-hydroxy-4-p-hydroxybenzyl-1,2,3,4-tetrahydro-1-naphthol 
• 79754-58-8 7-hydroxy-4-p-hydroxybenzyl-3,4-dihydronaphthalen-1(2H)-one 
• 79813-33-5 (+/-)-sequirin D 
• 79813-32-4 (+/-)-di-O-methylsequirin D 
• 79754-51-1 4,5-bis-p-methoxyphenyl-5-oxopentanoic acid 

Relevant academic research and scientific papers

Visible light-mediated arylalkylation of allylic alcohols through concomitant 1,2-aryl migration

A photocatalytic process for selective arylalkylation of allylic alcohols with α-bromo diethyl malonate has been developed. The reaction provided a straightforward approach to synthesize α-aryl-β-alkylated ketones via unique 1,2-aryl migration. The procedure is highlighted by its operational simplicity and mild reaction conditions.

Synthesis of 5-p-Hydroxybenzyl-5,6-dihydro-2-naphthol, (+/-)-Sequirin D

A high-yield six-step synthesis of sequirin D (1a), a naturally occurring norlignan, is described.Michael addition of deoxyanisoin (2) to acrylonitrile gives a ketonitrile (3), which on Wolff-Kishner reduction is reduced and hydrolysed in situ to 4,5-bis-