80398-85-2Relevant academic research and scientific papers
STRAIN AND SELECTIVITY: PARTNERS FOR ORGANIC SYNTHESIS
Trost, Barry M.
, p. 139 - 150 (2007/10/02)
The development of two new small-ring conjunctive reagents, (E)-2-(hydrohymethyl)cyclopropyl phenyl sulphide and 1,1-bis(benzenesulphonyl)cyclopropane, are reported.The former permits a synthesis of 2,4-disubstituted cyclobutanones and (E)-4-phenylthio-4-
Bifunctional Cyclopropyl Reagents: Stereocontrolled Approach to Vinyl Sulfides and Chemodifferentiated 1,4-Dicarbonyl Systems
Trost, Barry M.,Ornstein, Paul L.
, p. 748 - 751 (2007/10/02)
The use of (E)-2-(hydroxymethyl)cyclopropyl phenyl sulfide as a useful conjunctive reagent, particularly in a stereocontrolled synthesis of vinyl sulfides, is reported.
A CHEMOSELECTIVE DESULFURIZATION METHOD VIA HOMOGENEOUS NICKEL CATALYSIS
Trost, Barry M.,Ornstein, Paul L.
, p. 3463 - 3466 (2007/10/02)
Isopropylmagnesium bromide in the presence of bis-(triphenylphosphino)-nickel(II) chloride reduces vinyl sulfides stereospecifically to the corresponding olefins without overreduction - a process which serves as a key step in the synthesis of the sex pheromone of the Douglas fir tussock moth.
