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Trimethyl-[(1S,2S)-2-phenylsulfanyl-2-((E)-styryl)-cyclopropylmethoxy]-silane is a complex organic compound characterized by its unique molecular structure. It features a cyclopropane ring with a methyl group attached to the oxygen atom, a phenylsulfanyl group, and a styryl group, which is a vinylbenzene moiety. The compound is a chiral molecule, with the (1S,2S) configuration indicating that both chiral centers have the same configuration. This specific arrangement of atoms赋予es the compound distinct stereochemical properties. The presence of a trimethylsilyl group suggests potential applications in organic synthesis, particularly as a protecting group or in reactions involving silicon-based reagents. Its structure and properties make it a compound of interest in the fields of organic chemistry and materials science.

80398-95-4

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80398-95-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 80398-95-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,0,3,9 and 8 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 80398-95:
(7*8)+(6*0)+(5*3)+(4*9)+(3*8)+(2*9)+(1*5)=154
154 % 10 = 4
So 80398-95-4 is a valid CAS Registry Number.

80398-95-4Relevant academic research and scientific papers

STRAIN AND SELECTIVITY: PARTNERS FOR ORGANIC SYNTHESIS

Trost, Barry M.

, p. 139 - 150 (2007/10/02)

The development of two new small-ring conjunctive reagents, (E)-2-(hydrohymethyl)cyclopropyl phenyl sulphide and 1,1-bis(benzenesulphonyl)cyclopropane, are reported.The former permits a synthesis of 2,4-disubstituted cyclobutanones and (E)-4-phenylthio-4-

Bifunctional Cyclopropyl Reagents: Stereocontrolled Approach to Vinyl Sulfides and Chemodifferentiated 1,4-Dicarbonyl Systems

Trost, Barry M.,Ornstein, Paul L.

, p. 748 - 751 (2007/10/02)

The use of (E)-2-(hydroxymethyl)cyclopropyl phenyl sulfide as a useful conjunctive reagent, particularly in a stereocontrolled synthesis of vinyl sulfides, is reported.

A CHEMOSELECTIVE DESULFURIZATION METHOD VIA HOMOGENEOUS NICKEL CATALYSIS

Trost, Barry M.,Ornstein, Paul L.

, p. 3463 - 3466 (2007/10/02)

Isopropylmagnesium bromide in the presence of bis-(triphenylphosphino)-nickel(II) chloride reduces vinyl sulfides stereospecifically to the corresponding olefins without overreduction - a process which serves as a key step in the synthesis of the sex pheromone of the Douglas fir tussock moth.

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