80398-89-6

Upstream product

• 108-98-5 thiophenol 
• 80398-84-1 (E)-2-(hydroxymethyl)cyclopropyl phenyl sulphide 
• 63196-76-9 Methyl trans-2-phenylthiocyclopropanecarboxylate 
• 29193-71-3 methyl 4-(phenylsulfanyl)butanoate 
• 80398-84-1 (2-Phenylsulfanyl-cyclopropyl)-methanol 
• 80398-85-2 1-Phenylsulfanyl-3-oxa-bicyclo[3.1.0]hexan-2-ol 
• 1754-88-7 ethylenetriphenylphosphorane 
• 75-77-4 chloro-trimethyl-silane 
• 1530-32-1 ethyltriphenylphosphonium bromide 

Downstream Products

• 80399-01-5 Trimethyl-((1E,4E)-4-phenylsulfanyl-hepta-1,4-dienyloxy)-silane 
• 80575-01-5 [(E)-1-(3,3-Diethoxy-propyl)-but-1-enylsulfanyl]-benzene 
• 80575-02-6 [(E)-1-(3,3-Dimethoxy-propyl)-but-1-enylsulfanyl]-benzene 
• 18492-65-4 7,7-diethoxy-hept-3c-ene 
• 80399-01-5 Trimethyl-((1E,4E)-4-phenylsulfanyl-hepta-1,4-dienyloxy)-silane 

Relevant academic research and scientific papers

STRAIN AND SELECTIVITY: PARTNERS FOR ORGANIC SYNTHESIS

The development of two new small-ring conjunctive reagents, (E)-2-(hydrohymethyl)cyclopropyl phenyl sulphide and 1,1-bis(benzenesulphonyl)cyclopropane, are reported.The former permits a synthesis of 2,4-disubstituted cyclobutanones and (E)-4-phenylthio-4-

Bifunctional Cyclopropyl Reagents: Stereocontrolled Approach to Vinyl Sulfides and Chemodifferentiated 1,4-Dicarbonyl Systems

The use of (E)-2-(hydroxymethyl)cyclopropyl phenyl sulfide as a useful conjunctive reagent, particularly in a stereocontrolled synthesis of vinyl sulfides, is reported.

A CHEMOSELECTIVE DESULFURIZATION METHOD VIA HOMOGENEOUS NICKEL CATALYSIS

Isopropylmagnesium bromide in the presence of bis-(triphenylphosphino)-nickel(II) chloride reduces vinyl sulfides stereospecifically to the corresponding olefins without overreduction - a process which serves as a key step in the synthesis of the sex pheromone of the Douglas fir tussock moth.