81396-46-5

Upstream product

• 78-94-4 methyl vinyl ketone 
• 93-91-4 1-phenylbutan-1,3-dione 
• 431-03-8 dimethylglyoxal 
• 768-03-6 Phenyl vinyl ketone 
• 100-52-7 benzaldehyde 
• 4393-06-0 1-Phenyl-2-propen-1-ol 

Downstream Products

• 52313-43-6 3-acetyl-1-phenyl-pentane-1,4-dione 
• 43020-09-3 1-(5-methyl-2-phenylfuran-3-yl)ethan-1-one 
• 66685-28-7 (2,5-dimethylfuran-3-yl)(phenyl)methanone 

Relevant academic research and scientific papers

Michael addition reactions of α-acyloxy nitrile anions

The Michael addition reactions of α-acyloxy nitrile anions with Michael acceptors are followed by a shift of the acyl group to the α-carbon of the Michael acceptor. Michael acceptors such as acrylates, acrylonitrile and methyl vinyl ketone can be used. Ac

N-Heterocyclic carbene-catalyzed double acylation of enones with benzils

Thiazolium carbene-catalyzed reaction of aromatic 1,2-diketones with enones in aprotic solvents gave double acylation products in good yields, whereas hydroacylation products formed by Stetter reaction were not detected at all. These results suggested the generation of aroyloxyenamine species from the 1,2-diketones instead of hydroxyenamines (Breslow intermediates). This journal is

EINE NICHT ERWARTETE UMLAGERUNGSREAKTION VON VERZWEIGTEN TRIKETONEN

Heating 2-acyl-alkane-1,4-diones 1 to temperatures above 120 deg C causes an acylgroupmigration leading to 3-acyl-alkane-1,4-diones.