81434-73-3Relevant academic research and scientific papers
Infrared Laser Techniques to Study the Structure and Dynamics of Transient Species
Woodin, R. L.,Kaldor, A.
, p. 269 - 276 (1987)
Infrared multiple photon laser induced chemistry has moved over the past ten years between the extremes of heralding truly intramolecular selective chemistry and being merely a laboratory curiosity.The maturing of infrared multiple photon excitation (IRMPE) now finds IRMPE used routinely in a variety of experiments including spectroscopy, chemical kinetics, thermodynamics and laser driven synthesis.Continuously tunable infrared laser sources now allow a much wider range of molecules to be excited, and the photophysics of IRMPE to be probed in greater detail, than was possible with only limited line tunability.Examples of both the pfotophysics of IRMPE and applications to kinetics and spectroscopy are discussed, including vibrational photodissociation spectra of isolated metal clusters.
Study of Hydroxyl Reactions with Methanol and Ethanol by Laser-induced Fluorescence
Meier, U.,Grotheer, H. H.,Riekert, G.,Just, Th.
, p. 325 - 327 (2007/10/02)
Temperature dependences of the overall rate constants were measured for the reactions CH3OH + OH (1) and C2H5OH + OH (2) from 300 to 1000 K.Branching ratios for reactions (1) and (2) were determined at 298 K and secondary reactions of the product radicals were investigated.A rate constant for the combined reaction/deactivation of OH (v = 1) by CH3OH was derived. - Keywords: Chemical Kinetics / Mass Spectrometry / Radicals / Spectroscopy, Ultraviolet
