81569-44-0

Basic information

• Product Name: Methyl 4-methyl-5-thiazolecarboxylate
• Synonyms: 4-METHYLTHIAZOLE-5-CARBOXYLIC ACID METHYL ESTER;methyl 4-methyl-1,3-thiazole-5-carboxylate;METHYL 4-METHYL-5-THIAZOLYL FORMATE;METHYL 4-METHYLTHIAZOLE-5-CARBOXYLATE;Methyl,1-4-methyl-5-thiazolecarboxylate;Methyl 4-methyl-5-thiazolecarboxylate;5-Thiazolecarboxylicacid, 4-Methyl-, Methyl ester
• CAS NO: 81569-44-0
• Molecular Formula: C₆H₇NO₂S
• Molecular Weight: 157.19
• Mol File: 81569-44-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 221.3 ºC at 760 mmHg
• Flash Point: 87.7 ºC
• Appearance: /
• Density: 1.244 g/cm³
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Methyl 4-methyl-5-thiazolecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 4-methyl-5-thiazolecarboxylate(81569-44-0)
• EPA Substance Registry System: Methyl 4-methyl-5-thiazolecarboxylate(81569-44-0)

Safety Data

• Hazardous Substances Data: 81569-44-0(Hazardous Substances Data)

Usage

Chemical Properties

white to light yellow crystal powde

Upstream product

• 7647-01-0 hydrogenchloride 
• 20485-41-0 4-methylthiazole-5-carboxylic acid 
• 20582-55-2 ethyl 4-methylthiazole-5-carboxylate 
• 3829-80-9 2-amino-4-methylthiazole-5-carboxylic acid methyl ester 
• 105-45-3 acetoacetic acid methyl ester 
• 115-08-2 thiocarboxamide 
• 4755-81-1 methyl 2-chloroacetoacetate 
• 186581-53-3 diazomethane 
• 67-56-1 methanol 
• 54237-09-1 4-methylthiazole-5-carboxylic acid chloride 

Downstream Products

• 1361941-36-7 methyl 2-(tert-butyl)-4-methylthiazole-5-carboxylate 
• 1361941-35-6 methyl 4-(bromomethyl)-2-(tert-butyl)thiazole-5-carboxylate 
• 1361386-78-8 methyl 2-tert-butyl-4-((2-methyl-3-(4,4,5,5-tetramethyl-1,3,2dioxa-borolan-2-yl)phenylamino)methyl)thiazole-5-carboxylate 
• 1361386-79-9 2-tert-butyl-4-((2-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenylamino)methyl)thiazole-5-carboxylic acid 
• 1977-06-6 (4-methyl-1,3-thiazol-5-yl)methanol 
• 103987-43-5 N-benzenesulfonyl-N'-(4-methyl-thiazole-5-carbonyl)-hydrazine 
• 82294-70-0 4-methyl-1,3-thiazole-5-carbaldehyde 
• 123039-52-1 4-bromo-1-(4-methyl-5-thiazolyl)-1-butanone hydrochloride 
• 80087-60-1 1-Methyl-5-[3-(4-methyl-5-thiazolyl)carbonylpropyl]thio-1,2,3,4-tetrazole 
• 123039-51-0 α-<(4-methyl-5-thiazolyl)carbonyl>-γ-butyrolactone 
• 89179-72-6 4-methyl-thiazole-5-carboxylic acid hydrazide 

Relevant articles and documents

Dimethyl sulfoxide-accelerated reductive deamination of aromatic amines with t-BuONO in tetrahydrofuran

An efficient method for the conversion of aryl amines into arenes by a one-pot reductive deamination has been achieved. It was found the reductive deamination using t-BuONO in tetrahydrofuran could be accelerated by dimethyl sulfoxide and provided the deamination products with good yields under mild conditions. A plausible mechanism is discussed.