82009-22-1Relevant academic research and scientific papers
Heterocyclic Nitrogen-containing Electron-pair Donor Ligands: A Thermochemical Study of Adducts with Zinc, Cadmium, and Mercury Chlorides
Airoldi, Claudio,Silva, Maria L. C. P.,Chagas, Aecio P.
, p. 1913 - 1916 (1986)
The standard enthalpies (ΔH0R/kJ*mol-1) of the reactions MCl2(s)+nL(s,l)->MCL2.nL(s) for ligands pyridine (py), 2,2'-bipyridine (bipy), and 1,10-phenanthroline (phen) were measured calorimetrically at 298.15 K, giving: ZnC
REACTION OF ALKYL BROMIDES WITH STYRENE IN THE PRESENCE OF A NICKEL CATALYST
Lebedev, S. A.,Lopatina, V. S.,Luk'yanova, T. V.,Berestova, S. S.,Shifrina, R. R.,et al.
, p. 652 - 656 (2007/10/02)
Alkyl bromides enter into reaction with styrene in the presence of a nickel catalyst to form the products from substitution of the vinyl hydrogen of styrene, i.e., E-1-phenyl-1-alkenes.A high yield of E-1-phenyl-1-alkenes is promoted by the use of seconda
ON THE REACTIVITY OF V(η-C6H3Me3-1,3,5)2I
Aviles, T.,Teuben, J.H.
, p. 39 - 44 (2007/10/02)
V(η-C6H3Me3-1,3,5)2I reacts with reducing agents such as MeLi, Na or Na to yield the neutral complex V(η-C6H3Me3-1,3,5)2 in 70-75percent yield.Reaction of V(η-C6H3Me3-1,3,5)2I with compounds containing suitable donor atoms such as THF,
SYNTHESIS AND PROPERTIES OF COVALENT TRI- AND TETRAVALENT VANADIUM
Razuvaev, G.A.,Latyaeva, V.N.,Vyshinskaya, L.I.,Drobotenko, V.V.
, p. 169 - 182 (2007/10/02)
Reactions of VCl3*3THF with RMgX (R = Ph, CH2SiMe3, C6F5) in various ratios have been studied.The stable compounds R3V*THF (R = CH2SiMe3, C6F5) were obtained.The chemical properties of R3V*THF, R4V*2L (R = CH2Ph, L = Et2O; R = C6F5, L = THF) and (Me3SiCH2)4V were investigated.Cleavage of the vanadium-carbonium ?-bond occurs in reactions with H2O, HCl and HgCl2.The insertion of carbon dioxide into the vanadium-carbon ?-bond was investigated.A scheme for the derivatives of tri- and tetravalent vanadium is proposed.Oxidative addition to (C6F5)3V*THF by Ph3CCl and VCl3*3THF was also studied.
