82128-96-9Relevant articles and documents
CPO-27-M as heterogeneous catalysts for aldehyde cyanosilylation and styrene oxidation
Yao, Hong-Fei,Yang, Yang,Liu, Hui,Xi, Fu-Gui,Gao, En-Qing
, p. 57 - 65 (2014)
A series of isostructural 3D metal-organic frameworks of 2,5-dihydroxyterephthalate with different metal ions, CPO-27-M (or MOF-74-M, M = Co, Mg, Mn, Ni and Zn), have been studied as catalysts for cyanosilylation of aldehydes with trimethylsilylcyanide an
Zirconium-based MOF catalyst with double active sites and preparation method and application thereof
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Paragraph 0071; 0073; 0075-0079, (2021/06/09)
The invention discloses a zirconium-based MOF catalyst loaded with double active sites as well as a preparation method and an application of the zirconium-based MOF catalyst. The method comprises thefollowing steps: adding zirconium salt and an organic ligand into an organic solvent, taking organic acid as a regulator, and carrying out self-assembly reaction to obtain a metal organic framework; adding salicylaldehyde for aldehyde amine condensation to obtain chelating coordination sites, adding palladium salt, and performing coordination through an impregnation method; reducing the obtained MOF in hydrogen to obtain an MOF loaded with Pd nanoparticles; reacting MOF and zinc salt in an organic solvent, and obtaining the catalyst. The Pd-Zn-coated UiO-68-NH2-CH3 catalyst synthesized by thepreparation method disclosed by the invention has efficient catalytic activity in a tandem alcohol oxidation/aldehyde cyanosilylation reaction. According to the catalyst, a metal organic framework UiO-68-NH2-CH3 is constructed, Pd nanoparticles and Zn are loaded by taking the metal organic framework UiO-68-NH2-CH3 as a carrier, the loading capacity of the Pd nanoparticles is 4-8wt%, and the loading capacity of the Zn is 3-5wt%.
A new heterometallic MOF in cyanosilylation reaction, treatment and care management value in stroke by reducing oxidative stress damage
Chen, Shu-Rong,Li, Yi,Wu, Bi-Yu,Xu, Hui
, p. 43 - 49 (2020/01/21)
By employment the heterometallic strategy, a new highly porous metal-organic framework {(Me2NH2)[Mn3K2(TZIA)3-(H2O)3] '(DMF)4}n (1) was prepared via corresponding K(I)