82128-96-9Relevant articles and documents
CPO-27-M as heterogeneous catalysts for aldehyde cyanosilylation and styrene oxidation
Yao, Hong-Fei,Yang, Yang,Liu, Hui,Xi, Fu-Gui,Gao, En-Qing
, p. 57 - 65 (2014)
A series of isostructural 3D metal-organic frameworks of 2,5-dihydroxyterephthalate with different metal ions, CPO-27-M (or MOF-74-M, M = Co, Mg, Mn, Ni and Zn), have been studied as catalysts for cyanosilylation of aldehydes with trimethylsilylcyanide an
Constructing a triangular metallacycle with salen-Al and its application to a catalytic cyanosilylation reaction
Li, Bo,Li, Yang,Qiu, Huayu,Xu, Jun,Yin, Shouchun,Zhang, Jinjin,Zhang, Pengfei,Zhang, Yueyue
supporting information, p. 10399 - 10402 (2021/10/12)
A triangular metallosalen-based metallacycle was constructed in quantitative yield by the self-assembly of a 180° bis(pyridyl)salen-Al complex and a 60° diplatinum(ii) acceptor in a 1?:?1 stoichiometric ratio. This metallacycle was then successfully used to cyanosilylate a wide range of benzaldehydes with trimethylsilyl cyanide.
Zirconium-based MOF catalyst with double active sites and preparation method and application thereof
-
Paragraph 0071; 0073; 0075-0079, (2021/06/09)
The invention discloses a zirconium-based MOF catalyst loaded with double active sites as well as a preparation method and an application of the zirconium-based MOF catalyst. The method comprises thefollowing steps: adding zirconium salt and an organic ligand into an organic solvent, taking organic acid as a regulator, and carrying out self-assembly reaction to obtain a metal organic framework; adding salicylaldehyde for aldehyde amine condensation to obtain chelating coordination sites, adding palladium salt, and performing coordination through an impregnation method; reducing the obtained MOF in hydrogen to obtain an MOF loaded with Pd nanoparticles; reacting MOF and zinc salt in an organic solvent, and obtaining the catalyst. The Pd-Zn-coated UiO-68-NH2-CH3 catalyst synthesized by thepreparation method disclosed by the invention has efficient catalytic activity in a tandem alcohol oxidation/aldehyde cyanosilylation reaction. According to the catalyst, a metal organic framework UiO-68-NH2-CH3 is constructed, Pd nanoparticles and Zn are loaded by taking the metal organic framework UiO-68-NH2-CH3 as a carrier, the loading capacity of the Pd nanoparticles is 4-8wt%, and the loading capacity of the Zn is 3-5wt%.
Porous Co-MOF for cyanosilylation reaction and protective effect in child bronchial pneumonia by reducing the inflammatory response and IL-12 production in immune cells
Yu, Hongjun,Li, Heng,Zhang, Qiang,Shao, Yue,Wang, Yong-Ji
, (2020/01/21)
A new porous metal–organic framework (MOF) with the chemical formula of [Co2(FDDI)(H2O)3](DMA)4 (1, H4FDDI = 5,5′-(9H-fluorene-2,7-diyl) showing the ttd-type topological structure has been prepared by
A new heterometallic MOF in cyanosilylation reaction, treatment and care management value in stroke by reducing oxidative stress damage
Chen, Shu-Rong,Li, Yi,Wu, Bi-Yu,Xu, Hui
, p. 43 - 49 (2020/01/21)
By employment the heterometallic strategy, a new highly porous metal-organic framework {(Me2NH2)[Mn3K2(TZIA)3-(H2O)3] '(DMF)4}n (1) was prepared via corresponding K(I)
Temperature-induced Sn(II) supramolecular isomeric frameworks as promising heterogeneous catalysts for cyanosilylation of aldehydes
Sheng, Kai,Fan, Li-Ming,Tian, Xue-Fei,Gupta, Rakesh Kumar,Gao, Linna,Tung, Chen-Ho,Sun, Di
, p. 182 - 186 (2019/12/24)
Two novel Sn(II) supramolecular isomeric frameworks, with the identical formula of {(NH2Me2)2[Sn(BDC)(SO4)]}n, Sn-CP-1-α (1) and Sn-CP-1-β (2) (H2BDC=terephthalic acid) were synthesized und
Multinuclear Zn(II)-arylhydrazone complexes as catalysts for cyanosilylation of aldehydes
Aliyeva, Vusala A.,Guseinov, Firudin I.,Ma, Zhen,Mahmudov, Kamran T.,Pombeiro, Armando J. L.,Tagiev, Dilgam B.,Zubkov, Fedor I.
, (2020/02/15)
Three known multinuclear Zn(II)-arylhydrazone complexes, [Zn{(CH3)2SO}(H2O)(L1)] (1), [Zn2(CH3OH)2(μ-L2)2] (2) and [Zn4(μ-OH)2(1κO:2κO
Porous Cu(II)-organic framework for solvent-free cyanosilylation and anti-gastric cancer activity by inducing cell apoptosis
Fan, Shi-Jie,Sun, Ren,Li, Di,Liu, Yang
, p. 2855 - 2865 (2020/06/21)
A novel metal–organic framework (MOF) containing Cu(II) ions with the chemical formula of {[Cu(L)2(H2O)2](DMF)3}n (1) was successfully prepared by solvothermal reaction method using metal Cu2+/s
New Co(II)-organic framework for cyanosilylation reactions and treatment effect against esophageal cancer by inhibiting cancer cell viability, migration, and invasion
Du, Nan,Huang, Yongdong,Liu, Zihao,Wang, Changgao,Wang, Xiaoman,Zan, Hui
, p. 1 - 14 (2020/07/14)
A new metal–organic framework with the chemical formula [Co2(ptptc)·(H2O)3](MeOH) (1) was synthesized using Co(NO3)2· 6H2O and terphenyl-3,3″,5,5″-tetracarboxylic acid (H4ptptc)
A ketone-functionalized Zn-MOF for solvent-free cyanosilylation of aldehyde and treatment activity against osteosarcoma trough increasing Mg63 cells autophagy
Peng, Tao,Jia, Peng,Wang, Rui,Feng, Haoyu,Han, Xiao-Ming
, p. 2235 - 2249 (2020/10/02)
In this work, 5,5′-carbonyldiisophthalic acid (H4cipa) was used as a ligand to react with Zn(NO3)2·6H2O in a mixed solvent of DMF and water to prepare a new metal-organic framework (MOF) with the chemical formul
