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83395-39-5

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83395-39-5 Usage

Uses

Allyl 1H-imidazole-1-carboxylate can be used:To prepare allyl enol carbonate derivatives by reacting with ketone enolates and boron trifluoride etherate.In the acylation of a mixture of primary and secondary alcohols.

General Description

Allyl 1H-imidazole-1-carboxylate is an organic reagent used to introduce carboxyallyl groups to nucleophilic nitrogen, oxygen, and carbon centers. It is used in the acylation reactions of enolates and nitrogen compounds. Further, it can also be used in the synthesis of carbonates and allyl esters.

Check Digit Verification of cas no

The CAS Registry Mumber 83395-39-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,3,9 and 5 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 83395-39:
(7*8)+(6*3)+(5*3)+(4*9)+(3*5)+(2*3)+(1*9)=155
155 % 10 = 5
So 83395-39-5 is a valid CAS Registry Number.

83395-39-5 Well-known Company Product Price

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  • Aldrich

  • (748811)  Allyl 1H-imidazole-1-carboxylate  95%

  • 83395-39-5

  • 748811-5G

  • 329.94CNY

  • Detail
  • Aldrich

  • (748811)  Allyl 1H-imidazole-1-carboxylate  95%

  • 83395-39-5

  • 748811-25G

  • 1,970.28CNY

  • Detail

83395-39-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name prop-1-en-2-yl imidazole-1-carboxylate

1.2 Other means of identification

Product number -
Other names allyl carbonylimidazolide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:83395-39-5 SDS

83395-39-5Relevant articles and documents

Design and Synthesis of Cyclic Mismatch-Binding Ligands (CMBLs) with Variable Linkers by Ring-Closing Metathesis and their Photophysical and DNA Repeat Binding Properties

Mukherjee, Sanjukta,Dohno, Chikara,Nakatani, Kazuhiko

, p. 11385 - 11396 (2017)

Cyclophane-containing bis(2-amino-1,8-naphthyridine) moieties attached to variable linkers at the C2-position (linker B) were synthesized as cyclic mismatch-binding ligands (CMBLs). Ring-closing metathesis (RCM) is used as a key step for the introduction

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Dihydroquinolinones

Trost, Barry M.,Nagaraju, Anugula,Wang, Feijun,Zuo, Zhijun,Xu, Jiayi,Hull, Kami L.

supporting information, (2019/03/19)

A palladium-catalyzed decarboxylative asymmetric allylic alkylation (Pd-DAAA) of benzo-fused and non-benzo-fused δ-valerolactams is disclosed. This methodology gives access to chiral lactams bearing C3-quaternary stereocenters, which are central to many n

Studies on the enantioselective synthesis of carbazolones as intermediates in aspidosperma and kopsia alkaloid synthesis

Gartshore, Christopher J.,Lupton, David W.

, p. 882 - 890 (2013/09/12)

Two strategies for the assembly of homochiral carbazolones have been investigated. The first exploited desymmetrisation of 1,3-cyclohexadione derivatives however this failed to deliver satisfactory outcomes. An orthogonal route exploiting palladium catalysed decarboxylative allylation of racemic carbazolone β-ketoesters has been developed. Herein we report full details on the development of this reaction and clarify apparent discrepancies between our preliminary reports and those of Shao.

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